bis(3-allylsalicylal-2'-hydroxyanilinato)dicopper(II) | 1450751-01-5

• 英文名称: bis(3-allylsalicylal-2'-hydroxyanilinato)dicopper(II)
• CAS: 1450751-01-5
• 化学式: C₃₂H₂₆Cu₂N₂O₄
• 分子量: 629.661
• InChiKey: WTIVRQVUUGUMNB-CQGBIQBTSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3-allylsalicylal-2'-hydroxyaniline 在 acetate monohydrate 作用下， 以 甲醇 为溶剂， 反应 2.0h， 以80%的产率得到bis(3-allylsalicylal-2'-hydroxyanilinato)dicopper(II)
  参考文献：
  名称：

  Synthesis, X-ray spectral, and magnetochemical study of copper complexes based on tridentate azomethines of 3-allylsalicylaldehyde

  摘要：

  Tridentate azomethine ligands (H2L) based on 3-allylsalicylaldehyde and o-aminophenol, o-aminothiophenol, or 2-ethylamino-5-nitroaniline were synthesized and identified by IR and H-1 NMR spectroscopies. The structure of complexes (Ia-Ic) was studied by magnetochemistry and EXAFS spectroscopy. Complexes Ia and Ib (X = O, S) are binuclear and exhibit antiferromagnetic exchange interaction: 2J = -36.5 and -950 cm(-1), respectively. Complex Ic (X = NC2H5) is mononuclear (mu(eff) = 1.75 mu(B) at 275 K and does not change as temperature decreases).

  DOI：

  10.1134/s1070328413040039