(methyldiphenyl-l5-phosphaneyl)gallium(IV) iodide | 201227-88-5

• 英文名称: (methyldiphenyl-l5-phosphaneyl)gallium(IV) iodide
• CAS: 201227-88-5
• 化学式: C₁₃H₁₃GaI₃P
• 分子量: 650.656
• InChiKey: POLILAWZKKLHPN-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氢化镓 、 碘 、 二苯基甲氧基膦 以 乙醚 为溶剂， 生成 (methyldiphenyl-l5-phosphaneyl)gallium(IV) iodide
  参考文献：
  名称：

  Adducts of GaI3 and InI3 with Ph3P and Ph3As

  摘要：

  Adducts Ph3PGaI3 and Ph3AsGaI3 obtained by adding the ligands to Et2OGaI3 have been investigated by Ga-71 NMR, IR/Raman spectroscopy and X-ray diffraction. Et2OInI3 with Ph3P gives (Ph3P)(3)(InI3)(2). Ph3As yields (Ph3As)(3)(InI3)(2) . H2O as rhombohedral crystals whose structure was solved by X-ray diffraction. Both these indium complexes contain Ph3EInI3 molecules alongside five-coordinate adducts (Ph3E)(2)InI3 with the Ph3E ligands attached in axial sites by long and unequal bonds to a planar InI3 unit. Vibrational assignments are made for Ph3PGaI3, Ph3AsGaI3, Ph3EInI3 and (Ph3E)(2)InI3 (E = P or As). (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00221-0