| 344315-14-6

• CAS: 344315-14-6
• 化学式: C₂₉H₂₉AlN₂P₂
• 分子量: 494.492
• InChiKey: WXRHAOGHDBNNOX-MBSCIIMOSA-N

反应信息

• 作为产物：
  描述：

  (Z,3E)-N-diphenylphosphanyl-3-diphenylphosphanyliminoprop-1-en-1-amine 、 三甲基铝 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Malonodinitrile CH₂(CN)₂ as Synthon for the Preparation of Unprecedented N-Metalla- and N-Phosphino-β-diimine Ligands

  摘要：

  Unprecedented N-phosphino-beta -diimine ligands 4 and 5 have been prepared from a facile one-pot synthesis using malonodinitrile, CH2(CN)(2), the Schwartz reagent [Cp2Zr(H)Cl](n) (1), and the corresponding chlorophosphines R2PCl 2 and 3. An alkyl aluminum complex and the corresponding bidentate lithium salt ligand have been isolated. We showed that the reactivity of the N-phosphino-beta -diimine compound 4 and that of the corresponding N-thiophosphino-beta -diimine derivative 6 with HCl are completely different. The chemistry reported suggests unique and interesting chelating behavior which may differ from that of existing beta -diimine ligands.

  DOI：

  10.1021/om010105q