| 264916-62-3

• CAS: 264916-62-3
• 化学式: C₁₃H₃₉Al₄Cl₂N₇O
• 分子量: 488.331
• InChiKey: FBDQASWCPQIWHF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  aluminium chloride dimer 、 lithium dimethylamide 以 petroleum ether 为溶剂， 生成
  参考文献：
  名称：

  Isolation of new polynuclear aluminium amides; trinuclear [AlCl(MeNCH2CH2NMe)2(Al(NMe2)Cl)(Al(NMe2)2)] and fluxional adamantane-like [Al4Cl2(NMe2)6(NMe)O]

  摘要：

  In attempted transamination reactions involving [Al-2(NMe2)(6)] and the amines, N,N'-dimethylethylenediamine, DMEDA, or diethylenetriamine, DETA, insoluble white powders were formed. Two unexpected compounds, trinuclear [AlCl(MeN-CH2CH2NMe)(2)(Al(NMe2)Cl)(Al(NMe2)(2))] (1) and adamantane-like [Al4Cl2(NMe2)(6)(NMe2)(6)(NMe)O] 2) were isolated in similar reactions where the aluminium amide sample [Al-2(NMe3)(6)] contained some 1% residual chloride. Compound 2 was also identified (by NMR and mass spectroscopy) as the major product from the reaction between Al2Cl6 and LiNMe2 (1:5) in the presence of traces of water. The compounds 1 and 2 have been characterized by X-ray crystallography, mass spectroscopy and NMR. Variable temperature solution phase proton NMR shows that there is inversion at nitrogen in the bridging amides in adamantanoid structure 2. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00667-1