1,7-[NMePh(CH2Cl)]2B12H10 | 950578-69-5

• 英文名称: 1,7-[NMePh(CH2Cl)]2B12H10
• CAS: 950578-69-5
• 化学式: C₁₆H₃₀B₁₂Cl₂N₂
• 分子量: 451.066
• InChiKey: SJURNAFXCDLDCU-ACHIHNKUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  decaborane 、 N-甲基甲酰苯胺 、 三氯氧磷 以 not given 为溶剂， 以54%的产率得到[tetrabutylammonium][N(CH3)(C6H5)(CH2Cl)]B12H11
  参考文献：
  名称：

  Reaction of closo-dodecaborate anion B12H 12 2− with iminium salts

  摘要：

  The reaction of the closo-dodecaborate anion with iminium salts was studied. The iminium salts were either formed in situ or introduced into the reaction in an individual state. Mono-and disubstituted products with an exopolyhedral boron-nitrogen bond were found to form. The structures of compounds 1,7-[NMe2(CH2Cl)](2)B12H10 and 1,7-[MeNPh(CH2Cl)](2)B12H10 were determined using X-ray crystallography.

  DOI：

  10.1134/s0036023606110064