[Ru(Br)(py(bu)S4)] | 868556-19-8

• 英文名称: [Ru(Br)(py(bu)S4)]
• 英文别名: [Ru(Br)(2,6-bis(3,5-di-tert-butyl-2-sulfanylphenylthiomethyl)pyridine(-2H))]
• CAS: 868556-19-8
• 化学式: C₃₅H₄₇BrNRuS₄
• 分子量: 791.003
• InChiKey: KAKJIYFCGCAIMK-UHFFFAOYSA-K

反应信息

• 作为反应物：
  描述：

  [Ru(Br)(py(bu)S4)] 以 not given 为溶剂， 生成 [Ru(py(bu)S4)]2Br2
  参考文献：
  名称：

  Visible Light Induced Reversible Extrusion of Nitric Oxide from a Ruthenium(II) Nitrosyl Complex:  A Facile Delivery of Nitric Oxide

  摘要：

  The new ruthenium compound [Ru(NO)(pysiS4)]Br (3) (pysiS4 = 2,6-bis(3-triphenylsilyl-2-sulfanylphenylthiomethyl)pyridine), containing sterically bulky SiPh3 groups ortho to the thiolate donors, has been synthesized. In solution, 3 releases NO efficiently on exposure to visible light (lambda >/= 455 nm) at room temperature to afford [Ru(Br)(pysiS4)] (4). Treatment of 4 with NO yielded exclusively 3 without any metal-bound side reaction.

  DOI：

  10.1021/ja053758x