[Ti(η(5)-NC4(CH3)4)(CH3)Cl2] | 380609-00-7

• 英文名称: [Ti(η(5)-NC4(CH3)4)(CH3)Cl2]
• CAS: 380609-00-7
• 化学式: C₉H₁₅Cl₂NTi
• 分子量: 256.011
• InChiKey: RPXBIBLAUDAPSN-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  [Ti(η(5)-NC4(CH3)4)Cl3] 、 甲基锂 以 乙醚 、 甲苯 为溶剂， 以42%的产率得到[Ti(η(5)-NC4(CH3)4)(CH3)Cl2]
  参考文献：
  名称：

  Synthesis and characterisation of [M(η5-NC4Me4)(CH2Ph)3] (M=Ti, Zr, Hf) and [Ti(η5-NC4Me4)(Me)Cl2]. Structural determination and bonding of [Ti(η5-NC4Me4)(Me)Cl2] depicting an agostic interaction

  摘要：

  The complex [Ti(eta (5)-NC4Me4)(Me)Cl-2] (1) has been synthesised and characterised. Based upon the X-ray structure and ab initio theoretical calculations performed on the model complex [Ti(eta (5)-NC4H4)(Me)Cl-2] an agostic interaction has been postulated. The synthesis and characterisation of [M(eta (5)-NC4Me4)(CH2Ph)(3)] (M = Ti, 2; Zr, 3; Hf, 4) complexes are also described as well as the possibility of similar agostic interactions, which are discussed from the NMR data and the comparison with analogue carbocyclic compounds. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00824-5