| 74486-65-0

• CAS: 74486-65-0
• 化学式: C₅₀H₅₀ClOP₂Pt
• 分子量: 959.427
• InChiKey: FXCUHOQRFSFLQR-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  (3,5-di-tert-butyl-4-hydroxyphenyl)Pt(PPh₃)2Cl 在 油酸甲酯 、 氧气 作用下， 以 not given 为溶剂， 生成
  参考文献：
  名称：

  摘要：

  2,6-Di-tert-butylphenols containing the Pt-SnCl3 and Pt-GeCl3 groups in the para position exert a dual effect on the oxidation of methyl oleate by molecular oxygen. Initially, these compounds act as antioxidants producing the corresponding phenoxyl radicals whose decomposition is accompanied by elimination of SnCl2 and GeCl2, which are oxidation promoters.

  DOI：

  10.1023/a:1011398109034

文献信息

• ——
  作者：E. R. Milaeva、D. B. Shpakovsky、E. N. Shaposhnikova、E. V. Grigor"ev、N. T. Berberova、M. P. Egorov

  DOI：10.1023/a:1011333516900

  日期：——

  sigma -Aryl trans-bistriphenylphosphine complexes based on 2,6-di-tert-butylphenol containing Pt-SnCl3, Pt-GeCl3 groups were synthesized, Oxidation of these compounds gives the corresponding phenoxyl radicals, which were studied by ESR spectroscopy, The transformation of the diamagnetic complexes to the paramagnetic state is accompanied by cleavage of the Pt-Sn, Pt-Ge bonds and by elimination of SnCl2, GeCl2.