μ-cyclo[1,6-bis(naphthalene diethylphosphoramidite)]bis[pentacarbonylmolybdenum(0)] | 847556-85-8

• 英文名称: μ-cyclo[1,6-bis(naphthalene diethylphosphoramidite)]bis[pentacarbonylmolybdenum(0)]
• 英文别名: μ-[3,7-bis(diethylamino)-1(1,6),5(1,6)-dinaphthalene-2,4,6,8-tetraoxa-3,7-diphosphacyclooctaphane]bis [penta carbo nyl molybdenum(0)]
• CAS: 847556-85-8
• 化学式: C₃₈H₃₂Mo₂N₂O₁₄P₂
• 分子量: 994.505
• InChiKey: WVDOFUDEPYNZKV-OXBGUEGTSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 molybdenum hexacarbonyl 以 1,4-二氧六环 为溶剂， 反应 9.0h， 以79%的产率得到μ-cyclo[1,6-bis(naphthalene diethylphosphoramidite)]bis[pentacarbonylmolybdenum(0)]
  参考文献：
  名称：

  基于 1,6-二羟基萘作为双齿配体的萘并磷杂环芳烃合成钼 (0) 羰基配合物

  摘要：

  双核钼 (0) 羰基配合物是基于包含 1,6-二羟基萘片段和二乙酰胺接头的萘并膦环芳烃合成的。研究了合成配位体系的理化和光谱特性。

  DOI：

  10.1007/s11172-018-2246-9

文献信息

• 2,6- and 1,6-Dihydroxynaphthalenes in the Synthesis of Phosphacyclophanes
  作者：E. N. Rasadkina、P. V. Slitikov、M. S. Mel'nik、A. I. Stash、V. K. Bel'skii、E. E. Nifant'ev

  DOI：10.1023/b:rugc.0000045868.37162.87

  日期：2004.7

  Peculiar phosphacyclophanes were prepared from symmetrical 2,6- and unsymmetrical 1,6-dihydroxynaphthalenes. The position of the hydroxy groups in dihydroxynaphthalenes considerably affects their reactivity, the structure of the phosphacyclophanes obtained, and also the disproportionation of bisphosphoramidites. Oxo and thio derivatives of these phosphoramidites as well as their molybdenum complexes were prepared.