[(2-(diethylamino)cyclopentadienyl)ruthenium(II)(1,3,5-triaza-7-phosphaadamantane)2(MeCN)]PF6 | 850813-22-8

• 英文名称: [(2-(diethylamino)cyclopentadienyl)ruthenium(II)(1,3,5-triaza-7-phosphaadamantane)2(MeCN)]PF6
• CAS: 850813-22-8
• 化学式: C₂₅H₄₅N₈P₂Ru*F₆P
• 分子量: 765.668
• InChiKey: HTPJHPVVTJCIHO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(2-(diethylamino)cyclopentadienyl)ruthenium(II)(1,3,5-triaza-7-phosphaadamantane)2(MeCN)]PF6 、 水 以 水 为溶剂， 生成 [(cyclopentadien(CH2)2NHEt2)Ru(1,3,5-triaza-7-phosphaadamantane)(acetonitrile)(μ-(1,3,5-triaza-7-phosphaadamantane(H)1,3,5-triaza-7-phosphaadamantane))(acetonitrile)(1,3,5-triaza-7-phosphaadamantane)Ru(cyclopentadien(CH2)2NHEt2)](PF6)5*NH4PF6*4H2O
  参考文献：
  名称：

  Water soluble ruthenium cyclopentadienyl and aminocyclopentadienyl PTA complexes as catalysts for selective hydrogenation of α,β-unsaturated substrates (PTA=1,3,5-triaza-7-phosphaadamantane)

  摘要：

  A series of half-sandwich Ru-cyclopentadienyl derivatives containing the cage-like water soluble monodentate phosphine 1,3,5-triaza-7-phosphaadamantane (PTA) was synthesized and tested in aqueous phase or biphasic homogeneous hydrogenation of activated olefins via hydrogen transfer or under hydrogen pressure at mild conditions. The hydrogen transfer results show higher activity for the Cp* derivatives (Cp* = C5Me5) than for the corresponding Cp complexes (CP = C5H5). Under H, pressure, all complexes show high selectivity to C=C double bond hydrogenation. The X-ray crystal structure featuring a protonated 2-aminoethylcyclopentadienyl Ru complex was also determined. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2004.06.030
• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 [(2-(diethylamino)cyclopentadienyl)ruthenium(II)Cl(1,3,5-triaza-7-phosphaadamantane)2] 、 乙腈 以 乙腈 为溶剂， 以75%的产率得到[(2-(diethylamino)cyclopentadienyl)ruthenium(II)(1,3,5-triaza-7-phosphaadamantane)2(MeCN)]PF6
  参考文献：
  名称：

  Water soluble ruthenium cyclopentadienyl and aminocyclopentadienyl PTA complexes as catalysts for selective hydrogenation of α,β-unsaturated substrates (PTA=1,3,5-triaza-7-phosphaadamantane)

  摘要：

  A series of half-sandwich Ru-cyclopentadienyl derivatives containing the cage-like water soluble monodentate phosphine 1,3,5-triaza-7-phosphaadamantane (PTA) was synthesized and tested in aqueous phase or biphasic homogeneous hydrogenation of activated olefins via hydrogen transfer or under hydrogen pressure at mild conditions. The hydrogen transfer results show higher activity for the Cp* derivatives (Cp* = C5Me5) than for the corresponding Cp complexes (CP = C5H5). Under H, pressure, all complexes show high selectivity to C=C double bond hydrogenation. The X-ray crystal structure featuring a protonated 2-aminoethylcyclopentadienyl Ru complex was also determined. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2004.06.030