lithium(I)(H2O)3[Ga(III)(ethylenediaminetetraacetic acid(-4H))] | 1221506-38-2

• 英文名称: lithium(I)(H2O)3[Ga(III)(ethylenediaminetetraacetic acid(-4H))]
• CAS: 1221506-38-2
• 化学式: C₁₀H₁₈GaLiN₂O₁₁
• 分子量: 418.924
• InChiKey: AVIRIUZCZSYKHE-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Ga(III)(ethylenediaminetetraacetic acid(-3H))(H2O)] 、 lithium carbonate 以 水 为溶剂， 生成 lithium(I)(H2O)3[Ga(III)(ethylenediaminetetraacetic acid(-4H))]
  参考文献：
  名称：

  Crystal structure of Li(H2O)3[GaEdta]

  摘要：

  The ethylenediaminetetraacetate complex Li(H2O)(3)[Ga(Edta)] was synthesized and its crystal structure composed of octahedral (Ga(Edta)(-) anions connected to the Li(H2O) (3) (+) ion through the oxygen atom was studied. Five of the six hydrogen atoms of water molecules are involved in weak hydrogen bonds with the oxygen atoms of four Ga(Edta)(-) complexes, the complex anion is hydrogen-bonded to five water molecules. In addition, shortened contacts C(221)-H(22A)aEuro broken vertical bar O(112) between the Ga(Edta)(-) anions were found. As a result, the molecular packing in the crystal is determined by the three-dimensional lace of hydrogen bonds. The results are compared with published data for the lithium salts of Bi(III), Sb(III), Fe(III), Ni(II), and Hg(II) ethylenediaminetetraacetates.

  DOI：

  10.1134/s1070328409090024