(F-trans-Cl)-[TaFCl3MeCN](1+) | 52647-29-7

• 英文名称: (F-trans-Cl)-[TaFCl3MeCN](1+)
• CAS: 52647-29-7
• 化学式: C₄H₆Cl₃FN₂Ta
• 分子量: 388.41
• InChiKey: SBTMPPRTJAHUQB-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  stannous fluoride 、 五氯化钽 、 乙腈 以 乙腈 为溶剂， 生成 (F-trans-MeCN)-[TaFCl3(MeCN)2](1+) 、 (F-trans-Cl)-[TaFCl3MeCN](1+)
  参考文献：
  名称：

  摘要：

  Reactions of SnF2 and SbF3 with TaF5 and TaCl5 in acetonitrile and dimethyl sulfoxide were studied by F-19 and Sn-119 NMR. It was found that SnF2 and SbF3 behave as fluorine donors for tantalum(V). The anionic and cationic tantalum fluorochloride complexes form in acetonitrile, while [TaF6](-) predominates in dimethyl sulfoxide. Tin(II) occurs in solution in the form of fluorine-containing polymeric cations.

  DOI：

  10.1023/a:1011333414834