Fe((η5-C5H4)C(Me)NNC(H)(Cl2C6H3))2 | 571166-51-3

• 英文名称: Fe((η5-C5H4)C(Me)NNC(H)(Cl2C6H3))2
• CAS: 571166-51-3
• 化学式: C₂₈H₂₂Cl₄FeN₄
• 分子量: 612.168
• InChiKey: RVHPACGQUZRZHW-ABYQTUHUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  sodium tetrachloropalladate(II) 、 Fe((η5-C5H4)C(Me)NNC(H)(Cl2C6H3))2 、 三苯基膦 在 Na(CH₃COO)*3H₂O 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 以53%的产率得到Pd2(Fe((η5-C5H3)C(Me)NNC(H)(C6H3Cl2))2Cl2(PPh3)2
  参考文献：
  名称：

  Activation of σ(C–H) bonds of [Fe{(η5-C5H4)–C(Me)N–NC(H)(C6H3–2,6-R)}2] (with R=Cl or H) promoted by palladium(II)

  摘要：

  The synthesis, characterisation and the study of the reactivity of the novel and bifunctional ferrocenyl Schiff bases [Fe{(eta(5)-C5H4)-C(Me)=N-N=C(H)(C6H3-2,6-R-2)}(2)] (with R = Cl or H) with palladium(II) salts under different experimental conditions are reported. The treatment of Na-2[PdCl4], Na(CH3COO) .3H(2)O and the corresponding ligand [Fe{(eta(5)-C5H4)-C(Me)=N-N= C(H)(C(6)H(3-)2,6-R-2)}(2)] (with R = Cl or H) (in a 2:2:1 molar ratio) in methanol for 6 days followed by the addition of triphenylphosphine (PPh3), and a SiO2 column chromatography, allowed the isolation of the two isomers (meso- and D,L- forms) of the heterotrimetallic complexes of general formula [Pd-2{Fe[(eta(5)-C5H3)-C(Me)=N-N=C(H)(C6H5-2,6-R-2)](2)}Cl-2(PPh3)(2)], (with R = Cl or H). (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00137-2
• 作为产物：
  描述：

  1, 1'-diacetylferrocene dihydrazone 、 2,6-二氯苯甲醛 以 乙醇 为溶剂， 以65.5%的产率得到Fe((η5-C5H4)C(Me)NNC(H)(Cl2C6H3))2
  参考文献：
  名称：

  Activation of σ(C–H) bonds of [Fe{(η5-C5H4)–C(Me)N–NC(H)(C6H3–2,6-R)}2] (with R=Cl or H) promoted by palladium(II)

  摘要：

  The synthesis, characterisation and the study of the reactivity of the novel and bifunctional ferrocenyl Schiff bases [Fe{(eta(5)-C5H4)-C(Me)=N-N=C(H)(C6H3-2,6-R-2)}(2)] (with R = Cl or H) with palladium(II) salts under different experimental conditions are reported. The treatment of Na-2[PdCl4], Na(CH3COO) .3H(2)O and the corresponding ligand [Fe{(eta(5)-C5H4)-C(Me)=N-N= C(H)(C(6)H(3-)2,6-R-2)}(2)] (with R = Cl or H) (in a 2:2:1 molar ratio) in methanol for 6 days followed by the addition of triphenylphosphine (PPh3), and a SiO2 column chromatography, allowed the isolation of the two isomers (meso- and D,L- forms) of the heterotrimetallic complexes of general formula [Pd-2{Fe[(eta(5)-C5H3)-C(Me)=N-N=C(H)(C6H5-2,6-R-2)](2)}Cl-2(PPh3)(2)], (with R = Cl or H). (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00137-2