| 176442-35-6

• CAS: 176442-35-6
• 化学式: C₁₀₆H₁₀₂O₁₂P₂Rh₄S₄
• 分子量: 2169.8
• InChiKey: DBFIMDQPZQZDNK-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 2-叔丁基苯酚亚磷酸盐 以 二氯甲烷 为溶剂， 以44.2%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of rhodium complexes containing atropisomeric sulfur ligands. Structure of [{Rh₂(µ-L)(CO)₃[P(OC₆H₄Bu^t-o)₃]}₂](H₂L = 1,1′-binaphthalene-2,2′-dithiol)

  摘要：

  The addition of the atropisomeric racemic sulfur compound 1,1'-binaphthalene-2,2'-dithiol (H(2)L) to a dichloromethane solution of [{Rh(mu-OMe)(cod)}(2)] (cod = cycloocta-1,5-diene) afforded the dithiolate-bridged complexes [{Rh-2(mu-L)(cod)(2)}(n)] (n = 21 or 12). These reacted with carbon monoxide to give the dinuclear tetracarbonyl complex [Ru-2(mu-L)(CO)(4)] 3. The reaction of 3 with PR(3) provided the mixed-ligand complexes [{Rh-2(mu-L)(CO)(2)(PR(3))(2)}(2)] (R = Ph 4 or C(6)H(11)5) and [{Rh-2(mu-L)(CO)(3)(PR(3))}(2)] 6 [R = P(OC(6)H(4)Bu(t)-o)(3)]. The crystal structure of 6 was determined by X-ray diffraction.

  DOI：

  10.1039/dt9960000969