| 251110-43-7

• CAS: 251110-43-7
• 化学式: C₄₄H₅₇NO₃Ti₃
• 分子量: 791.581
• InChiKey: ZUBWOTHICLKTBY-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (η5-pentamethylcyclopentadienyl)3Ti3O3CH 、 N-苄叉苯胺 以 正己烷 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Photochemical incorporation of N-benzylidene(phenyl)amine into the complex [{Ti(η5-C5Me5)(η-O)}3(μ3-CH)] as a model of the titanium oxide surface†

  摘要：

  The photochemical incorporation of PhCHNPh to the metal oxide model [{TiCp*(µ-O)}3(µ3-CH)] (Cp* = η5-C5Me5) occurs by breaking of the CN imine bond and formation of µ-imido and σ-alkenyl groups on the [Ti3O3] core; the crystal structure of the obtained product, [{TiCp*(µ-O)}3(µ-NPh)(CHCHPh)], was determined by X-ray diffraction.

  DOI：

  10.1039/a905129e