[(η5-cyclopentadienyl)Fe(C13H5(Et)2(OMe)(tert-butyl-dimethylsilyl))] | 873785-74-1

• 英文名称: [(η5-cyclopentadienyl)Fe(C13H5(Et)2(OMe)(tert-butyl-dimethylsilyl))]
• CAS: 873785-74-1
• 化学式: C₂₉H₃₈FeO₂Si
• 分子量: 502.552
• InChiKey: BBZXEXOLWPNNGT-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [(η5-cyclopentadienyl)Fe(C13H5(Et)2(OMe)(tert-butyl-dimethylsilyl))Cr(CO)3] 以 further solvent(s) 为溶剂， 以68%的产率得到[(η5-cyclopentadienyl)Fe(C13H5(Et)2(OMe)(tert-butyl-dimethylsilyl))]
  参考文献：
  名称：

  Reactions of complex ligands part 106. Heterobimetallic fused arenes: Chromium-templated benzannulation of a ferrocene-type metal carbene

  摘要：

  The heterobimetallic iron cyclopentadienyl(indenyl)carbene chromium complex 3 was synthesized from 5-bromoindene by via metalation with C5H5Fe(CO)(2)I, photodecarbonylation and chromium carbene functionalization of the pi-bromoindenyl(cyclopentadienyl)iron intermediate 2. The chromium-templated benzannulation with 3-hexyne afforded syn- and anti-diastereomers of heterobimetallic hydroquinoid arene Cr(CO)(3) complexes 4a and 4b which were characterized by X-ray, spectroscopic and electrochemical means. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.07.081