trans-(3,5-di-tert-butyl-4-hydroxyphenyl)-bis(triphenylphosphine)platinum chloride | 74486-63-8

• 英文名称: trans-(3,5-di-tert-butyl-4-hydroxyphenyl)-bis(triphenylphosphine)platinum chloride
• CAS: 74486-63-8
• 化学式: C₅₀H₅₁ClOP₂Pt
• 分子量: 960.435
• InChiKey: NRFDLXKLANYCSP-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  tin(ll) chloride 、 trans-(3,5-di-tert-butyl-4-hydroxyphenyl)-bis(triphenylphosphine)platinum chloride 以 氯仿 为溶剂， 以58%的产率得到trans-(3,5-di-tert-butyl-4-hydroxyphenyl)-bis(triphenylphosphine)platinumtintrichloride
  参考文献：
  名称：

  摘要：

  sigma -Aryl trans-bistriphenylphosphine complexes based on 2,6-di-tert-butylphenol containing Pt-SnCl3, Pt-GeCl3 groups were synthesized, Oxidation of these compounds gives the corresponding phenoxyl radicals, which were studied by ESR spectroscopy, The transformation of the diamagnetic complexes to the paramagnetic state is accompanied by cleavage of the Pt-Sn, Pt-Ge bonds and by elimination of SnCl2, GeCl2.

  DOI：

  10.1023/a:1011333516900