sodium (η(2)-allylbenzene)trichloroplatinate(II) | 250250-05-6

• 英文名称: sodium (η(2)-allylbenzene)trichloroplatinate(II)
• CAS: 250250-05-6
• 化学式: C₉H₁₀Cl₃Pt*Na
• 分子量: 442.607
• InChiKey: VRZNSCNFEQCULJ-UHFFFAOYSA-K

反应信息

• 作为反应物：
  描述：

  吡啶 、 sodium (η(2)-allylbenzene)trichloroplatinate(II) 以 水 为溶剂， 以86%的产率得到trans-dichloro(η(2)-allylbenzene)(pyridine)platinum(II)
  参考文献：
  名称：

  Synthesis and Characterization of an Unusual Platinum(II) Alkene Complex with an η²-Arene Interaction

  摘要：

  Dichloro(9,10-dihydro-9,10-ethenoanthracene)platinum(II) has been synthesized and characterized by MMR spectroscopy and X-ray crystallography. The crystal structure shows that the alkene fragment serves as an anchor to place one of the aromatic rings in close enough proximity for an eta(2)-arene-platinum interaction. Thus, the ethenoanthracene functions as a bidentate ligand.

  DOI：

  10.1021/om990272e
• 作为产物：
  描述：

  烯丙苯 、 sodium platinum(II) chloride*4H2O=Natriumplatin(II)-chlorid*4H2O 以 丙醇 为溶剂， 以77%的产率得到sodium (η(2)-allylbenzene)trichloroplatinate(II)
  参考文献：
  名称：

  Synthesis and Characterization of an Unusual Platinum(II) Alkene Complex with an η²-Arene Interaction

  摘要：

  Dichloro(9,10-dihydro-9,10-ethenoanthracene)platinum(II) has been synthesized and characterized by MMR spectroscopy and X-ray crystallography. The crystal structure shows that the alkene fragment serves as an anchor to place one of the aromatic rings in close enough proximity for an eta(2)-arene-platinum interaction. Thus, the ethenoanthracene functions as a bidentate ligand.

  DOI：

  10.1021/om990272e