[(η(3)-C3H5)Pd(C9H8N3)] | 252955-03-6

• 英文名称: [(η(3)-C3H5)Pd(C9H8N3)]
• CAS: 252955-03-6
• 化学式: C₁₂H₁₃N₃Pd
• 分子量: 305.675
• InChiKey: MNKFXHMTAAXTDK-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  2-(3-methylpyridin-2-yl)-imidazole 在 NaHCO₃ 作用下， 以 二氯甲烷 、 氯仿 、 水 为溶剂， 生成 [(η(3)-C3H5)Pd(C9H8N3)]
  参考文献：
  名称：

  Interconvertible Cationic and Neutral Pyridinylimidazole η³-Allylpalladium Complexes. Structural Assignment by ¹H, ¹³C, and ¹⁵N NMR and X-ray Diffraction

  摘要：

  Interconvertible cationic pyridinylimidazole eta(3)-allylpalladium complex 2 and neutral pyridinylimidazolyl eta(3)-allylpalladium complex 3 were synthesized and their structures analyzed by H-1, C-13, and N-15 NMR and X-ray diffraction. Cationic 2 and neutral 3 can be changed into each other by deprotonation and protonation.

  DOI：

  10.1021/om990647w