[Pd(η3-CH2CMeCHMe)(μ-Cl)]2 | 12301-06-3

• 英文名称: [Pd(η3-CH2CMeCHMe)(μ-Cl)]2
• CAS: 12301-06-3
• 化学式: C₁₀H₁₈Cl₂Pd₂
• 分子量: 421.999
• InChiKey: XTXHMZKVHXSRDU-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  、 [Pd(η3-CH2CMeCHMe)(μ-Cl)]2 在 NaOH 作用下， 以 not given 为溶剂， 以90%的产率得到[Pd(η3-CH2CMeCHMe)(MeCOCHCMeNMe)]
  参考文献：
  名称：

  Synthesis and Characterization of Allyl(β-ketoiminato)palladium(II) Complexes:  New Precursors for Chemical Vapor Deposition of Palladium Thin Films

  摘要：

  Treatment of beta-ketoiminates with [(allyl)Pd(mu-Cl)](2) affords volatile, air-stable allyl(beta-ketoiminato)palladium(II) complexes. The structure of [(methallyl)Pd(Phacac)] (Phacac = MeCOCHCMeNPh) was determined by single-crystal X-ray diffraction. In solution H-1 NMR analyses indicate either a direct rotation of a planar allyl ligand about the allyl-palladium axis or a solvent-assisted exchange process involving the transient formation of a monodentate ketoiminato ligand. The physical properties of the complexes were modified by altering the B-ketoiminato or the eta(3)-allyl ligands. Some derivatives are liquid at room temperature and were known to be suitable for chemical vapor deposition of Pd thin films.

  DOI：

  10.1021/om980728c