(2,2'-bipyrimidine) disilver(I) nitrate | 1286739-87-4

• 英文名称: (2,2'-bipyrimidine) disilver(I) nitrate
• 英文别名: [Ag2(μ2-bipyrimidine)(μ-ONO2)2]
• CAS: 1286739-87-4
• 化学式: C₈H₆Ag₂N₆O₆
• 分子量: 497.909
• InChiKey: ZHQKOKZRWLMLSR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  silver nitrate 、 2 2'-联嘧啶 以 乙醇 、 水 为溶剂， 以85%的产率得到(2,2'-bipyrimidine) disilver(I) nitrate
  参考文献：
  名称：

  2D Bipyrimidine silver(I) nitrate: Synthesis, X-ray structure, solution chemistry and anti-microbial activity

  摘要：

  Synthesis and X-ray single crystal structure analysis of the compound {[Ag-2(mu(2)-bpym)(mu-O-NO3)(2)]}(n), (1), (where bpym = 2,2'-bipyrimidine) are presented. Compound (1) has a (6,3)-2D honeycomb structure with a tetrahedral coordination geometry around the Ag(I) ion. In contrary to the solid state structural investigation, ESI-MS for (1) in solution shows a strong peak at m/z 423.0269 which indicates that the [Ag(bpym)(2)](+) cation is dominating instead of [Ag-2(bpym))(2+). The anti-microbial activity of (1) was screened against 15 multi-drug resistant bacteria in comparison to silver(I) sulphadiazine and it showed a high activity against Burkholderia mallei which causes glanders; with a MIC value of 4 mu g/ml. Crown Copyright (C) 2011 Published by Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.01.022