[(η⁵-C₅Me₅)Ru(tert-butyl isocyanide)₂(N(tert-butyl)CN)] | 1448666-24-7

• 英文名称: [(η⁵-C₅Me₅)Ru(tert-butyl isocyanide)₂(N(tert-butyl)CN)]
• CAS: 1448666-24-7
• 化学式: C₂₅H₄₂N₄Ru
• 分子量: 499.705
• InChiKey: ROBINRPLWWXMFY-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  [(η⁵-C₅Me₅)Ru(tert-butyl isocyanide)₂(N(tert-butyl)CN)] 反应 6.0h， 生成 [(η⁵-C₅Me₅)Ru(tert-butyl isocyanide)₂(NCN-tert-butyl)]
  参考文献：
  名称：

  A Sandwich Zwitterionic Ruthenium Complex Bearing a Cyanamido Group

  摘要：

  A sandwich zwitterionic ruthenium complex (4) was prepared by an intramolecular 1,3-dipolar cydoaddition of the ruthenium azido isocyanide [CpMe5Ru(CNAr)(2)N-3] (2). The reaction involved a formal 1,3-migration mechanism along a highly conjugated system linking to a cyanamid group.

  DOI：

  10.1021/om400547r
• 作为产物：
  描述：

  [(η⁵-C₅Me₅)Ru(tert-butyl isocyanide)₂(NCN-tert-butyl)] 反应 12.0h， 生成 [(η⁵-C₅Me₅)Ru(tert-butyl isocyanide)₂(N(tert-butyl)CN)]
  参考文献：
  名称：

  A Sandwich Zwitterionic Ruthenium Complex Bearing a Cyanamido Group

  摘要：

  A sandwich zwitterionic ruthenium complex (4) was prepared by an intramolecular 1,3-dipolar cydoaddition of the ruthenium azido isocyanide [CpMe5Ru(CNAr)(2)N-3] (2). The reaction involved a formal 1,3-migration mechanism along a highly conjugated system linking to a cyanamid group.

  DOI：

  10.1021/om400547r