| 138319-15-0

• CAS: 138319-15-0
• 化学式: C₁₆H₂₂Cl₂N₂Ru
• 分子量: 414.34
• InChiKey: WDGPEGQSGRGSAS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-氨基-3-甲基吡啶 、 二氯(p-甲基异丙苯)钌(II) 二聚体 以 甲苯 为溶剂， 以47%的产率得到
  参考文献：
  名称：

  The reactions of [Ru(η6-arene)Cl2]2 compounds with a series of aminopyridine ligands: X-ray crystal structures of [Ru(η6-1,4-MeC6H4CHMe2)Cl2(NC5H4NH2)] and [Ru(η6-C16H16)Cl2(NC5H4NH2)]

  摘要：

  The reactions of the dimers [Ru(eta-6-arene)Cl2]2 (arene = C6H6, 1,4-MeC6H4CHMe2, [2(2)](1,4)C16H16) with a range of aminopyridine ligands have been investigated. These ligands can potentially coordinate to a single metal centre in a monodentate fashion through either pyridyl or amino nitrogen atoms, can chelate a single metal centre, or can bridge across two metal ions. Spectroscopic data collected on 12 compounds is exclusively consistent with monodentate coordination via the pyridyl nitrogen atoms. This mode of coordination has been conclusively established by X-ray structure determinations of the compounds [Ru(eta-6-1,4-MeC6H4CHMe2)Cl2(NC5H4NH2)] and Ru(eta-6-C16H16) Cl2(NC5H4NH2)].

  DOI：

  10.1016/s0277-5387(00)83792-4