| 272458-84-1

• CAS: 272458-84-1
• 化学式: C₃₈H₃₅Cl₂NO₃P₂Pd
• 分子量: 792.974
• InChiKey: XIONOVOIKKMPEH-FOVTZFJTSA-L

反应信息

• 作为产物：
  描述：

  二(氰基苯)二氯化钯 、 以 二氯甲烷 为溶剂， 以89%的产率得到
  参考文献：
  名称：

  P,N-Heterodifunctional ligands by selective Staüdinger reaction of β-substituted vinylazides with (Z)-1,2-bis(diphenylphosphanyl)ethene and formation of cyclometalled complexes of palladium(II) of these ligands — crystal and molecular structure of a new chiral cyclometallaphosphoraniminophosphane of palladium(II)

  摘要：

  Staudinger reactions of the beta-aryl-, heteroaryl- and ferrocenylvinylazides (2) with (Z)-1,2-bis(diphenylphosphanyl)ethene afford the P,N-ligands (3) in good yields. Reaction of 3 with dichlorobis(benzonitrile)palladium(II) leads to the Pd(II) metallacycle derivatives 5. The molecular structure of 5e has been determined by X-ray crystallography. The electrochemical behavior of this compound is also reported. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00731-7