| 49756-75-4

• CAS: 49756-75-4
• 化学式: F₅Xe*F₆Sb
• 分子量: 462.022
• InChiKey: SSMNQLHAJIFXFV-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 六氟锑酸硝 反应 24.0h， 以151 mg的产率得到
  参考文献：
  名称：

  [XeF ₅ ] ⁺ /Metal and [XeF ₅ ] ⁺ /Non‐Metal Mixed‐Cation Salts of Hexafluoridoantimonate(V)

  摘要：

  AbstractNew types of [XeF5]+ salts, i.e., NO2XeF5(SbF6)2 and XeF5[Cu(SbF6)3], are derived from reactions between XeF5SbF6 and NO2SbF6 or Cu(SbF6)2, respectively. The crystal structure of the former consists of [NO2]+ and [XeF5]+ cations and [SbF6]– anions. The main feature of the crystal structure of XeF5[Cu(SbF6)3] are rings of CuF6 octahedra that share apexes with SbF6 octahedra connected into an infinite tridimensional framework. This arrangement leads to the formation of cavities within which [XeF5]+ cations are located. Raman spectra of both [NO2]+/[XeF5]+ and [XeF5]+/Cu2+ mixed‐cation hexafluorido‐antimonates(V) are reported herein.

  DOI：

  10.1002/ejic.201500028
• 作为产物：
  描述：

  、 fluorine 生成
  参考文献：
  名称：

  [XeF ₅ ] ⁺ /Metal and [XeF ₅ ] ⁺ /Non‐Metal Mixed‐Cation Salts of Hexafluoridoantimonate(V)

  摘要：

  AbstractNew types of [XeF5]+ salts, i.e., NO2XeF5(SbF6)2 and XeF5[Cu(SbF6)3], are derived from reactions between XeF5SbF6 and NO2SbF6 or Cu(SbF6)2, respectively. The crystal structure of the former consists of [NO2]+ and [XeF5]+ cations and [SbF6]– anions. The main feature of the crystal structure of XeF5[Cu(SbF6)3] are rings of CuF6 octahedra that share apexes with SbF6 octahedra connected into an infinite tridimensional framework. This arrangement leads to the formation of cavities within which [XeF5]+ cations are located. Raman spectra of both [NO2]+/[XeF5]+ and [XeF5]+/Cu2+ mixed‐cation hexafluorido‐antimonates(V) are reported herein.

  DOI：

  10.1002/ejic.201500028

文献信息

• Single-crystal structure determination of NO2SbF6, XeF5SbF6 and XeF5Sb2F11
  作者：Zoran Mazej、Evgeny A. Goreshnik

  DOI：10.1016/j.jfluchem.2015.03.004

  日期：2015.7

  77(5) Å3, and Z = 2. Its crystal structure exhibits a different packing of the [NO2]+ and [SbF6]− ions than in the known crystal structure of NO2AsF6. The XeF5SbF6 compound is orthorhombic at 150 K, space group Pnma (No. 62), with a = 16.7159(6) Å, b = 8.1093(3) Å, c = 5.7576(2) Å, V = 780.47(5) Å3, Z = 4, and it is isotypic with the known XeF5MF6 crystal structures of M = Nb, Ru, and Pt. The unit cell

  NO 2 SbF 6在正交Kmmm空间群（第65号）中以150 K结晶，a  = 6.8119（7）Å，b  = 7.3517（7）Å，c  = 5.5665（5）Å，V  = 278.77（5）埃3，与ž  = 2。其晶体结构显示出的不同的包装中[NO 2 ] +和[的SbF 6 ] -离子比在NO的已知晶体结构2 ASF 6。XeF 5 SbF 6化合物在150 K时为正交晶，空间群为Pnma（编号62），具有一个 = 16.7159（6），b  = 8.1093（3）埃，c ^  = 5.7576（2）埃，V  = 780.47（5）3，Ž  = 4，并且它是同型与已知的氟化氙5 MF 6的晶体结构M ＝ Nb，Ru和Pt。XeF 5 Sb 2 F 11的晶胞在200 K下为三斜晶系，P1个¯空间组（第2个），其中a  = 8.5223（8）Å，b  = 8.5582（8）Å，c  =
• Influence of the Increasing Size of the M ²⁺ Cation on the Crystal Structures of XeF ₅ M(SbF ₆ ) ₃ (M = Ni, Mg, Cu, Zn, Co, Mn, Pd) and (XeF ₅ ) ₃ [Hg(HF)] ₂ (SbF ₆ ) ₇
  作者：Zoran Mazej、Evgeny Goreshnik

  DOI：10.1002/ejic.201600317

  日期：2016.7

  = Ca, Sr, Ba, Cr, Fe, Ag, Cd, and Hg were only successful for Hg, for which (XeF5)3[Hg(HF)]2(SbF6)7 was obtained. The crystal structures of XeF5M(SbF6)3 (M2+ = Mg, Co, Ni, Zn) and the low-temperature phase α-XeF5Mn(SbF6)3 are isotypic with the known XeF5Cu(SbF6)3. The main features of the crystal structures of β-XeF5Mn(SbF6)3 and β-XeF5Pd(SbF6)3 are similar to those of the other XeF5M(SbF6)3 compounds

  XeF5SbF6 和 M(SbF6)2（M2+ = Ni、Mg、Zn、Co、Mn、Pd）在无水 HF (aHF) 中以 1:1 的摩尔比反应生成 XeF5M(SbF6)3。所有六种结构都通过单晶 X 射线衍射在 150 K 下表征。对于 Mn，在 235 K 左右发生相变，Pd 在 260 和 296 K 之间发生相变。 类似的尝试制备新的 [XeF5]+/M2+ 混合阳离子盐，其中 M2+ = Ca、Sr、Ba、Cr、Fe， Ag、Cd 和 Hg 仅适用于 Hg，为此获得了 (XeF5)3[Hg(HF)]2(SbF6)7。XeF5M(SbF6)3 (M2+ = Mg, Co, Ni, Zn) 和低温相 α-XeF5Mn(SbF6)3 的晶体结构与已知的 XeF5Cu(SbF6)3 同型。β-XeF5Mn(SbF6)3 和 β-XeF5Pd(SbF6)3 晶体结构的主要特征与其他 XeF5M(SbF6)3
• Crystal Growth and Characterization of the Mixed‐Cation Rb ⁺ /[XeF ₅ ] ⁺ and Cs ⁺ /[XeF ₅ ] ⁺ Salts
  作者：Zoran Mazej、Evgeny Goreshnik

  DOI：10.1002/ejic.201700097

  日期：2017.6.8

  [SbF6]– and [BiF6]– has been confirmed by Raman spectroscopy. The low‐ and high‐temperature phases of Bi/Sb mixed‐anion compounds are isotypic with the corresponding A[XeF5][SbF6]2 (A = Rb, Cs) phases. No reactions were observed in the AAsF6 (A = Rb, Cs)/[XeF5][AsF6], ASbF6 (A = K, [H3O]+)/[XeF5][SbF6], and KBF4/[XeF5][SbF6] systems. In the CsBF4/[XeF5][SbF6] system, a metathetical reaction occurred

  在无水HF中，ASbF 6（A = Rb，Cs）和[XeF 5 ] [SbF 6 ]之间的摩尔比为1：1的反应在结晶后产生同型A [XeF 5 ] [SbF 6 ] 2化合物。A [XeF 5 ] [SbF 6 ] 2（A = Rb，Cs）盐在低温（α相，150 K）和环境温度（β相，296 K）下以两种晶体变型结晶。CsBiF 6和[XeF 5 ] [SbF 6 ]（1：1）之间的相似反应产生混合阳离子/混合阴离子化合物Cs [XeF 5 ] [Bi x Sb 1– x F 6] 2（x = 0.37–0.39）。光子原子的两个晶体学位置之一被Bi（约40％）和Sb（约60％）原子随机占据。[SbF 6 ] -和[BiF 6 ] -同时存在已通过拉曼光谱法确认。Bi / Sb混合阴离子化合物的低温和高温相与相应的A [XeF 5 ] [SbF 6 ] 2（A = Rb，Cs）相同型。在AAsF
• Mixed-Anion [AsF₆]⁻/[SbF₆]⁻ Salts of Cs⁺ and [XeF₅]⁺; Incommensurately Modulated Crystal Structures of [XeF₅][As_1-xSb_<i>x</i>F₆] (<i>x</i> ≈ 0.5 and 0.7)
  作者：Evgeny A. Goreshnik、Lev G. Akselrud、Zoran Mazej

  DOI：10.1021/acs.cgd.1c01429

  日期：2022.5.4

  molar ratios. The compositions of the grown single crystals as refined from the X-ray diffraction data correspond to Cs[As1-xSbxF6] (x = 0.13–0.87), which means that most probably all phases with x = 0–1 exist. They crystallize in the trigonal R 3̅ space group (no. 147). As5+ and Sb5+ are randomly distributed on the same crystallographic site. Crystal growth from aHF solutions of dissolved [XeF5][AsF6]

  CsAsF 6 /CsSbF 6的结晶在无水氟化氢 (aHF) 中以各种摩尔比进行。从 X 射线衍射数据中细化的生长单晶的组成对应于 Cs[As 1- x Sb x F 6 ] ( x = 0.13–0.87)，这意味着很可能所有具有x = 0–1的相存在。它们在三角R 3​​̅空间群中结晶（第 147 号）。As 5+和Sb 5+随机分布在同一晶位上。从溶解的 [XeF 5 ][AsF 6 ] 和 [XeF ]的 aHF 溶液中晶体生长5 ][SbF 6 ] 不同初始比例的混合物产生了 [XeF 5 ][As 1- x Sb x F 6 ] ( x ≈ 0.3 和 0.7) 盐的单晶。[XeF 5 ][As 0.5 Sb 0.5 F 6 ] 在低温（α 相， T < 180 K）和高温（β 相，T > 180 K）温度下以两种晶型结晶。α-[XeF 5 ][As 0.5 Sb 0.5 F
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: He: Edelgasverb., 1.8.3.3.1, page 85 - 87
  作者：

  DOI：——

  日期：——