fac-[Mn(CCCO2Me)(dppm)] | 852615-37-3

• 英文名称: fac-[Mn(CCCO2Me)(dppm)]
• CAS: 852615-37-3
• 化学式: C₃₂H₂₅MnO₅P₂
• 分子量: 606.433
• InChiKey: CFQZIOPJADYKDL-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  四氟硼酸-二乙醚络合物 、 fac-[Mn(CCCO2Me)(dppm)] 以 乙醚 、 二氯甲烷 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  Stepwise Formation of σ-Alkynyl, Vinylidene, and Vinylphosphonium Complexes of Manganese(I)

  摘要：

  Reaction of methyl propiolate with the diphosphinomethanide complex [Mn(CO)(4){(PPh2)(2)CH}] (1) produces simultaneously the insertion of the alkyne into the C-H bond, giving [Mn(CO)(4){(PPh2)(2)C-C(H)=C(CO2Me)H}] (2), and the deprotonation of the alkyne mediated by the diphosphinomethanide ligand, affording the σ-alkynyl derivative fac-[Mn(C=C-CO2Me)(CO)(3)(dppm)] (3). Protonation of 3 with HBF4 at 200 K affords the corresponding vinylidene compound fac-[Mn(C=C(H)CO2Me)(CO)(3)(dppm)]BF4 (5), which, on raising the temperature to 243 K, undergoes the spontaneous insertion of the vinylidene ligand into a Mn-P bond.

  DOI：

  10.1021/om050146c
• 作为产物：
  描述：

  {Mn(CO)4((Ph2P)2CH)} 、 丙炔酸甲酯 以 甲苯 为溶剂， 以30%的产率得到
  参考文献：
  名称：

  Stepwise Formation of σ-Alkynyl, Vinylidene, and Vinylphosphonium Complexes of Manganese(I)

  摘要：

  Reaction of methyl propiolate with the diphosphinomethanide complex [Mn(CO)(4){(PPh2)(2)CH}] (1) produces simultaneously the insertion of the alkyne into the C-H bond, giving [Mn(CO)(4){(PPh2)(2)C-C(H)=C(CO2Me)H}] (2), and the deprotonation of the alkyne mediated by the diphosphinomethanide ligand, affording the σ-alkynyl derivative fac-[Mn(C=C-CO2Me)(CO)(3)(dppm)] (3). Protonation of 3 with HBF4 at 200 K affords the corresponding vinylidene compound fac-[Mn(C=C(H)CO2Me)(CO)(3)(dppm)]BF4 (5), which, on raising the temperature to 243 K, undergoes the spontaneous insertion of the vinylidene ligand into a Mn-P bond.

  DOI：

  10.1021/om050146c