[(hydrido tris(3,5-dimethylpyrazolyl)borato)MoOCl(pyridine)] | 129238-87-5

• 英文名称: [(hydrido tris(3,5-dimethylpyrazolyl)borato)MoOCl(pyridine)]
• 英文别名: Tp*MoOCl(py)；(hydrotris(3,5-dimethylpylpyrazolyl)borate)MoOCl(pyridine)
• CAS: 129238-87-5
• 化学式: C₂₀H₂₇BClMoN₇O
• 分子量: 523.685
• InChiKey: NMIDLDNIFBNFTA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  {hydrotris(3,5-dimethyl-1-pyrazolyl)borate}dioxomolybdenum(VI)Cl 在 (C₆H₅)3P 作用下， 以 吡啶 为溶剂， 生成 [(hydrido tris(3,5-dimethylpyrazolyl)borato)MoOCl(pyridine)]
  参考文献：
  名称：

  Roberts, Sue A.; Young, Charles G.; Kipke, Cary A., Inorganic Chemistry, 1990, vol. 29, # 19, p. 3650 - 3656

  摘要：

  DOI：

文献信息

• Atom transfer chemistry and electrochemical behavior of Mo(VI) and Mo(V) trispyrazolylborate complexes: new mononuclear and dinuclear species
  作者：Andrew J Millar、Christian J Doonan、Les J Laughlin、Edward R.T Tiekink、Charles G Young

  DOI：10.1016/s0020-1693(02)01105-2

  日期：2002.9

  in the formation of [Tp*MoO(OPh)] 2 (μ-O) (Tp* = hydrotris(3,5-dimethylpyrazolyl)borate) in the reaction of Tp*MoO 2 (OPh) with PEt 3 in toluene (in contrast to the formation of phosphine oxide complexes in the Tp P r system), while hydrolysis of Tp*MoOCl 2 produced [Tp*MoOCl] 2 (μ-O). Reaction of Tp P r MoO 2 Cl with P(O i Pr) 3 produced [Tp P r MoOCl](μ-O)[Tp P r MoO(OH)]. The X-ray crystal structures

  Tp P r MoO 2 Cl（Tp P r =氢三（3-异丙基吡唑基）硼酸酯）与苯酚/ NEt 3或硫醇/ NEt 3混合物的复分解导致形成空气稳定的抗磁性顺式-二氧代-Mo（VI）配合物，Tp P r MoO 2 X（X = OC 6 H 4 sBu-2，OC 6 H 4 R-3（R = Me，t Bu），OC 6 H 4 R-4（R = Br，Et，OMe ），OC 6 H 3'Bu 2 -3,5，OC 6 H 3'BuMe-2,4，S n Bu，S s Bu）。通过支持制剂的分析，光谱和质谱法对复合物进行表征，这些配体支持存在的配体[IR：v（MoO 2）约930和900 cm-1，v（BH）2570-2480 cm-1，OAr 1605- 1500和1300-1250 cm-1]，并分配了分子对称性（1 H / 1 3 C NMR）。电化学研究显示可逆或准可逆（X = OC 6 H
• Xiao, Zhiguang; Bruck, Michael A.; Enemark, John H., Inorganic Chemistry, 1996, vol. 35, # 26, p. 7508 - 7515
  作者：Xiao, Zhiguang、Bruck, Michael A.、Enemark, John H.、Young, Charles G.、Wedd, Anthony G.

  DOI：——

  日期：——
• A Family of Dioxo−Molybdenum(VI) Complexes of N₂X Heteroscorpionate Ligands of Relevance to Molybdoenzymes
  作者：Brian S. Hammes、Bal S. Chohan、Justin T. Hoffman、Simon Einwächter、Carl J. Carrano

  DOI：10.1021/ic049130p

  日期：2004.11.1

  Four new Mo(Vl)-dioxo complexes of a family of N2X heteroscorpionate ligands are reported which, together with data already available for (Tp(R))(-), provide a unique example of a comprehensive set of isostructural, isoelectronic complexes differing only in one biologically relevant donor atom. A study of these complexes allows for a direct comparison of structural, spectroscopic, and oxygen atom transfer reactivity properties of the Mo(Vl)-dioxo center (of relevance to various families of molybdoenzymes) as a function of donor atom identity.