[zinc(II)](1-[(2-ethylaminoethylimino)methyl]naphthalen-2-olate]*CH3OH | 952481-56-0

• 英文名称: [zinc(II)](1-[(2-ethylaminoethylimino)methyl]naphthalen-2-olate]*CH3OH
• CAS: 952481-56-0
• 化学式: CH₄O*C₁₅H₁₈Br₂N₂OZn
• 分子量: 499.561
• InChiKey: AHPCCTHEGDHUOT-AMAREMMUSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  甲醇 、 1-[(2-ethylamino-ethylimino)-methyl]-naphthalen-2-ol 、 zinc dibromide 以 甲醇 、 水 为溶剂， 以42.6%的产率得到[zinc(II)](1-[(2-ethylaminoethylimino)methyl]naphthalen-2-olate]*CH3OH
  参考文献：
  名称：

  Synthesis, Crystal Structures and Antibacterial Activities of Two Schiff Base Zinc(II) Complexes

  摘要：

  Two new mononuclear Schiff base zinc(II) complexes, [ZnBr(2)L1] center dot CH3OH (1) and [ZnBr(2)L2] center dot H2O (2) (L1 = 1-[(2-ethylaminoethylimino) methyl] naphthalen-2-olate, L2 = 4 bromo-2-[(2=methylaminoethylimino)methyl] phenolate), have been obtained from a similar synthetic procedure. The complexes have been characterized by elemental analyses and single crystal X-ray determinations. In each of the complexes, the zinc(II) atom is four-coordinated by one imine N and one phenolate O atoms from a Schiff base ligand, and by two terminal Br atoms, forming a tetrahedral coordination. Except for the mononuclear zinc(II) complex moiety, complex 1 consists of a lattice MeOH molecule, while complex 2 consists of a lattice water molecule. Both of the lattice components in the complexes participate in the formation of hydrogen bonds. The Schiff base ligands and the two zinc(II) complexes showed potent antibacterial activities.

  DOI：

  10.1080/15533170601028165