cis-trans-cis-nitro-aqua-bis-[1-methyl-2(β-naphthylazo)imidazole]ruthenium(II) perchlorate | 1272975-34-4

• 英文名称: cis-trans-cis-nitro-aqua-bis-[1-methyl-2(β-naphthylazo)imidazole]ruthenium(II) perchlorate
• CAS: 1272975-34-4
• 化学式: C₂₈H₂₆N₉O₃Ru*ClO₄
• 分子量: 737.094
• InChiKey: JSHGLLZXMFGXQS-CDZLCHAASA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cis-trans-cis-nitro-aqua-bis-[1-methyl-2(β-naphthylazo)imidazole]ruthenium(II) perchlorate 、 乙腈 以 乙腈 为溶剂， 生成 cis-trans-cis-[Ru(nitro)(1-methyl-2(β-naphthylazo)imidazole)2(acetonitrile)] perchlorate
  参考文献：
  名称：

  Ruthenium(II) nitro-nitroso-bis-{1-(alkyl)-2-(β-napthylazo)imidazole}: Synthesis, spectroscopy, electrochemistry and reactivity

  摘要：

  Aquation of blue cis-trans-cis-[RuCl2(beta-NaiR)(2)] (1) leads to the synthesis of solvento species, blue-violet cis-trans-cis-[Ru(OH2)(2)(beta-NaiR)(2)](ClO4)(2) (2), [beta-NaiR = C10H7-N=N-C3H2-NN, abbreviated as N,N'-chelator, R = Me] that have been reacted with NaNO2 in warm EtOH resulting in violet dinitro complexes of the type, [Ru(NO2)(2)(beta-NaiR)(2)] (3). The nitrite complexes are useful synthons of electrophilic nitrosyls, and on triturating the dinitro compounds with cone. HClO4 nitro-nitrosyl derivatives, [Ru(NO2)(NO)(beta-NaiR)(2)](2+) (4) are isolated. The chemical oxidation of aqua complex (2) by excess aqueous eerie solution in 1 (N) H2SO4 leads to the spontaneous formation of a yellow colored species. The electrophilic behaviour of metal bound nitrosyl has been proved by reacting with a bicyclic ketone, camphor, containing an active methylene group and an arylhydrazone with an active methine group. The diazotization of the primary aromatic amines with a strongly electrophilic mononitrosyl complex in acetonotrile and dichloromethane solution was thoroughly studied. Electrocatalytic oxidation of benzyl alcohol was examined.

  DOI：

  10.1134/s0036023611010062
• 作为产物：
  描述：

  cis-trans-cis-nitro-nitroso-bis-[1-methyl-2(β-naphthylazo)imidazole]ruthenium(II) perchlorate 、 水 在 aniline 作用下， 以 二氯甲烷 为溶剂， 生成 cis-trans-cis-nitro-aqua-bis-[1-methyl-2(β-naphthylazo)imidazole]ruthenium(II) perchlorate
  参考文献：
  名称：

  Ruthenium(II) nitro-nitroso-bis-{1-(alkyl)-2-(β-napthylazo)imidazole}: Synthesis, spectroscopy, electrochemistry and reactivity

  摘要：

  Aquation of blue cis-trans-cis-[RuCl2(beta-NaiR)(2)] (1) leads to the synthesis of solvento species, blue-violet cis-trans-cis-[Ru(OH2)(2)(beta-NaiR)(2)](ClO4)(2) (2), [beta-NaiR = C10H7-N=N-C3H2-NN, abbreviated as N,N'-chelator, R = Me] that have been reacted with NaNO2 in warm EtOH resulting in violet dinitro complexes of the type, [Ru(NO2)(2)(beta-NaiR)(2)] (3). The nitrite complexes are useful synthons of electrophilic nitrosyls, and on triturating the dinitro compounds with cone. HClO4 nitro-nitrosyl derivatives, [Ru(NO2)(NO)(beta-NaiR)(2)](2+) (4) are isolated. The chemical oxidation of aqua complex (2) by excess aqueous eerie solution in 1 (N) H2SO4 leads to the spontaneous formation of a yellow colored species. The electrophilic behaviour of metal bound nitrosyl has been proved by reacting with a bicyclic ketone, camphor, containing an active methylene group and an arylhydrazone with an active methine group. The diazotization of the primary aromatic amines with a strongly electrophilic mononitrosyl complex in acetonotrile and dichloromethane solution was thoroughly studied. Electrocatalytic oxidation of benzyl alcohol was examined.

  DOI：

  10.1134/s0036023611010062