N-(3-prop-1-ene)-1,4,7-triazacyclononane molybdenum tricarbonyl | 334978-36-8

• 英文名称: N-(3-prop-1-ene)-1,4,7-triazacyclononane molybdenum tricarbonyl
• CAS: 334978-36-8
• 化学式: C₁₂H₁₉MoN₃O₃
• 分子量: 349.241
• InChiKey: FXODZUKGCOUUJI-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  N-allyl-1,4,7-triazacyclononane 、 molybdenum hexacarbonyl 以 二乙二醇二甲醚 为溶剂， 以62%的产率得到N-(3-prop-1-ene)-1,4,7-triazacyclononane molybdenum tricarbonyl
  参考文献：
  名称：

  N-Monofunctionalized 1,4,7-Triazacyclononane Macrocycles as Building Blocks in Inorganic Crystal Engineering

  摘要：

  The syntheses of N-(3-prop-1-ene)-1,4,7-triazacyclononane molybdenum tricarbonyl (2), N-(4-but-1-ene)-1,4,7-triazacyclononane molybdenum tricarbonyl (3), N-(3-prop-1-ene)-1,4,7-triazacyclononane molybdenum trioxide (5), N-(4-but-1-ene)-1,4,7-triazacyclononane molybdenum trioxide (6), N-(hydroxyethyl)-1,4,7-triazacyclononane molybdenum trioxide (7), and N-(2-methylpyridyl)-1,4,7-triazacyclononane molybdenum trioxide (8) have been achieved. The objective of this work is to systematically vary the functionality of the pendant group in order to create different crystal packing in the solid state. This is evidenced in comparing the structures of 1,4,7-triazacyclononane molybdenum trioxide (4) and 5-8, which were determined using X-ray crystallography. The synthesis and characterization of the new ligand N-(2-methylpyridyl)-1,4,7-triazacyclononane (L-5) is reported.

  DOI：

  10.1021/ic0006854