| 209164-12-5

• CAS: 209164-12-5
• 化学式: C₁₂H₃₆F₄Pt₄
• 分子量: 1036.73
• InChiKey: XQMISBLGRQYVKY-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 水 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Organoplatinum compounds VII

  摘要：

  The structural chemistry of organoplatinum clusters [Me3PtX](4) (X = halide) has been completed with the synthesis and X-ray investigation of [Me3PtF](4) (1) and its structural comparison to the well-known hydroxide [Me3PtOH](4) (2), all members of the 'organoplatinum cubane' family. Compound 1, long withstanding its attempted synthesis, has been obtained by the reaction of [Me3PtI](4) with XeF2 as a mild fluorinating agent in form of colourless crystals: space group I(4) over bar 3 m, Z = 2, a = 10.0878(7) Angstrom, R-1 = 0.0242, wR(2) = 0.0563. In order to discriminate 1 from its possible hydrolysis product, viz. [Me3PtOH](4) (2), the latter was also synthesised according to literature procedures and re-investigated by X-ray crystallography: colourless crystals, space group I(4) over bar 3 m, Z = 2, a = 10.1400(10) Angstrom, R-1 = 0.0238, wR(2) = 0.0586. NMR spectroscopic, mass spectrometric and, in part, IR data are reported for 1 and 2. A crystalline solid obtained from equimolar chloroform solutions of both 1 and 2 did not reveal any new structural features, e.g. lattice parameters. From this mixture one might have expected a possible formation of strong hydrogen bonds of the type Me3Pt-F ... H-O-PtMe3. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00481-1
• 作为产物：
  描述：

  二氟代氙 、 (trimethylplatinum(IV) iodide)4 以 二氯甲烷 为溶剂， 以74.7%的产率得到
  参考文献：
  名称：

  Organoplatinum compounds VII

  摘要：

  The structural chemistry of organoplatinum clusters [Me3PtX](4) (X = halide) has been completed with the synthesis and X-ray investigation of [Me3PtF](4) (1) and its structural comparison to the well-known hydroxide [Me3PtOH](4) (2), all members of the 'organoplatinum cubane' family. Compound 1, long withstanding its attempted synthesis, has been obtained by the reaction of [Me3PtI](4) with XeF2 as a mild fluorinating agent in form of colourless crystals: space group I(4) over bar 3 m, Z = 2, a = 10.0878(7) Angstrom, R-1 = 0.0242, wR(2) = 0.0563. In order to discriminate 1 from its possible hydrolysis product, viz. [Me3PtOH](4) (2), the latter was also synthesised according to literature procedures and re-investigated by X-ray crystallography: colourless crystals, space group I(4) over bar 3 m, Z = 2, a = 10.1400(10) Angstrom, R-1 = 0.0238, wR(2) = 0.0586. NMR spectroscopic, mass spectrometric and, in part, IR data are reported for 1 and 2. A crystalline solid obtained from equimolar chloroform solutions of both 1 and 2 did not reveal any new structural features, e.g. lattice parameters. From this mixture one might have expected a possible formation of strong hydrogen bonds of the type Me3Pt-F ... H-O-PtMe3. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00481-1