| 99128-06-0

• CAS: 99128-06-0
• 化学式: C₃₆H₄₄IInN₄
• 分子量: 774.497
• InChiKey: RUEGUPLQJGOXRU-YAJYDHHFSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  rhodium octaethylporphyrin-indium octaethylporphyrine 在 methyl iodide 作用下， 以 氘代苯 为溶剂， 生成 (C20H4N4(C2H5)8)rhodium(III)(methyl) 、
  参考文献：
  名称：

  Jones, Nancy L.; Carroll, Patrick J.; Wayland, Bradford B., Organometallics, 1986, vol. 5, # 1, p. 33 - 37

  摘要：

  DOI：

文献信息

• Gallium(III) and indium(III) octaethylporphyrin dimeric complexes with a single μ-hydroxo bridge: synthesis, structure and stability in anion-containing organic media
  作者：Paweł G Parzuchowski、Jeff W Kampf、Ewa Roźniecka、Yevgeniy Kondratenko、Elżbieta Malinowska、Mark E Meyerhoff

  DOI：10.1016/s0020-1693(03)00267-6

  日期：2003.11

  structures show that complexes of two metalloporphyrins are joined by a single protonated metaloxygenmetal bridge with a nearly 150° bridge angle. The porphyrin rings of the dimers form dihedral angles of 15° Ga(III) and 23° In(III). In contrast to previously reported analogous dimeric Mn(III) and Fe(III) structures, the porphyrin rings of the present dimers are twisted by a much greater torsion angle

  羟基桥接配合物（μ-羟基）-双（八乙基卟啉）高氯酸镓（III）[Ga（OEP）] 2 OH} ClO 4和（μ-羟基）-的合成及单晶X射线结构双（八乙基卟啉）铟（III）四[3,5-双-（三氟甲基）苯基]硼酸酯[In（OEP）] 2报告了OH} TFPB。这些配合物是通过用稀释的高氯酸滴定二氯甲烷中的单体金属卟啉物种或通过添加化学计量的四苯基硼酸酯衍生物盐来制备的。结构表明，两个金属卟啉的配合物通过单个质子化的金属-氧-金属桥连接在一起，桥的夹角接近150°。二聚体的卟啉环形成15°Ga（III）和23°In（III）的二面角。与先前报道的类似的二聚体Mn（III）和Fe（III）结构相反，本二聚体的卟啉环被扭转了更大的接近22°的扭转角。在二氯甲烷中，在高氯酸盐存在下观察到二聚体的高稳定性，但是发现随着卤素阴离子浓度的增加，二聚体物种解离成单体。这与最近报道的分别用聚合物薄膜中的Ga
• Action of alkyl halides on homo- and heteroporphyrin dimers involving a rhodium-indium bond, producing porphyrin complexes containing metal-carbon and metal-halide bonds
  作者：D. Lux、D. Daphnomili、A.G. Coutsolelos

  DOI：10.1016/s0277-5387(00)88149-8

  日期：1994.8

  The reactivity of the novel family of metalloporphyrin dimers containing a Rh-In bond towards alkyl halides is presented. The chemical reactivity of the homoleptic (same porphyrin ligand) and heteroleptic (different porphyrin ligand) porphyrin complexes with Rh-In metal-metal bond has been examined by photo- and thermal-processes in the presence of alkyl halides under anaerobic conditions in the dark. The photolytic and thermal reactions have been studied to define the polarity of the Rh-In single bond, as well as to identify the products. The presence of complexes containing Rh-C bonds in the reaction mixture detected by UV-vis spectroscopy postulated the formulation Rh(I)(-): --> In(III)(+) for the polarity of the metal-metal bond. In order to characterize the products we compare our spectroscopic results with those of the literature and those of authentic Rh-C containing complexes.