Re2(N,N'-di(3-methoxyphenyl)formamidine(1-))2Cl4 | 913355-99-4

• 英文名称: Re2(N,N'-di(3-methoxyphenyl)formamidine(1-))2Cl4
• 英文别名: Re2(DmAniF)2Cl4
• CAS: 913355-99-4
• 化学式: C₃₀H₃₀Cl₄N₄O₄Re₂
• 分子量: 1024.82
• InChiKey: XGSGWSQUDHVQOJ-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tetra-n-butylammonium octachlorodirhenate(III) 、 N,N'-二(3-甲氧基苯基)甲脒 以 neat (no solvent) 为溶剂， 以79%的产率得到Re2(N,N'-di(3-methoxyphenyl)formamidine(1-))2Cl4
  参考文献：
  名称：

  Synthesis and structural characterization of several dirhenium(III) compounds

  摘要：

  Reaction between Re-2(OAc)(4)Cl-2 and N,N'-dicyclohexylbenzamidine (HDCyBA) under molten conditions yielded Re-2(DCyBA)(2)Cl-4 (1); reaction of [Bu4N](2)[Re2Cl8] with N,N'-di(3-methoxyphenyl)formamidine (HDmAniF) resulted in Re-2(DmAniF)(2)Cl-4 (2); reaction of cis-Re-2(OAc)(2)Cl-4 with HDmAniF under reflux conditions resulted in cis-Re-2(OAc)(2)(DmAniF)(2)Cl-2 (3). Reaction between Re-2(OAc)(4)Cl-2 and alpha,alpha,alpha',alpha'-tetramethyl-1,3-benzenedipropionic acid (H(2)esp) under reflux conditions led to Re-2(esp)(2)Cl-2 (4). Crystallographic studies of compounds 1-4 revealed Re-Re bond lengths of 2.1679(6), 2.1804(5), 2.2468(7), and 2.2304(6) angstrom, respectively, which are consistent with the presence of Re-Re quadruple bond. Also reported are electrochemical properties of compounds 1-4. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.06.044