(Me2SiOSiMe2)[(η5-C9H6)Ru(CO)]2(μ-CO)2 | 910804-33-0

• 英文名称: (Me2SiOSiMe2)[(η5-C9H6)Ru(CO)]2(μ-CO)2
• CAS: 910804-33-0
• 化学式: C₂₆H₂₄O₅Ru₂Si₂
• 分子量: 674.785
• InChiKey: COUABAVYUJAZIW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  十二羰基三钌 、 1,3-bis(1-indenyl)-1,1,3,3-tetramethyldisiloxane 以 xylene 为溶剂， 以15%的产率得到(Me2SiOSiMe2)[(η5-C9H6)Ru(CO)]2(μ-CO)2
  参考文献：
  名称：

  Synthesis and structures of the silyl bridged bis(indenyl) diruthenium complexes and a novel indenyl nonanuclear ruthenium cluster Ru9(μ6-C)(CO)14(μ3-η5:η2:η2-C9H7)2

  摘要：

  Thermal treatment of C9H7SiMe2C9H7 and C9H7Me2SiOSiMe2C9H7 with Ru-3(CO)(12) in refluxing xylene gave the corresponding diruthenium complexes (E)[(eta(5)-C9H6)Ru(CO)](2)(mu-CO)(2) [E = Me2Si (1), Me2SiOSiMe2 (2)]. A desilylation product [(eta(5)-C9H7)Ru(CO)](2)-(mu-CO)(2) (3) was also obtained in the latter case. Similar treatment of C9H7Me2SiSiMe2C9H7 with Ru-3(CO)(12) gave a novel indenyl nonanuclear ruthenium cluster Ru-9(mu(6)-C)(CO)(14)(mu(3)-eta(5):eta(2):eta(2)-C9H7)(2) (5) with carbon-centered tricapped trigonal prism geometry, in addition to the diruthenium complex (Me2SiSiMe2)[(eta(5)-C9H6)Ru(CO)](2)(mu-CO)(2) (4) and the desilylation product 3. Complex 4 can undergo a thermal rearrangement to form the product [(Me2Si)(eta(5)-C9H6)Ru(CO)(2)](2) (6). The molecular structures of 1, 2, 4, 5, and 6 were determined by X-ray diffraction. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.05.030