| 757961-25-4

• CAS: 757961-25-4
• 化学式: C₂₅H₂₆ClNO₃PRh
• 分子量: 557.819
• InChiKey: ZLEZYENJMVTOIO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  di-μ-chloro-bis[bis(cyclo-octene)rhodium] 、 N-acetyl-N-methylglycine 2-(di-o-tolylphosphino)phenol ester 以 氘代苯 为溶剂， 生成
  参考文献：
  名称：

  Controlled oxidative addition of amino acid esters to Rh(I)

  摘要：

  The new sterically demanding phosphine 2-(di-o-tolylphosphino)phenol was prepared and used to create a series of esters with N-acylated amino acids. The phosphine-containing esters react within 30-60 min at room temperature with [(mu-Cl)Rh(cyclooctene)(2)](2) to give products of oxidative addition of the ester carbonyl-oxygen bond to the Rh center. The N-acyl carbonyl oxygen is bound to the Rh in these initial adducts, but is displaced upon addition of PMe3. Remarkably, both initial products and their PMe3 adducts are formed as single five-coordinate diastereomers in essentially quantitative yields. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00311-3