catena-poly[[[bis(2-pyridyl) ketone-N,N']-copper(II)]-di-μ-chloro] | 19319-95-0

• 英文名称: catena-poly[[[bis(2-pyridyl) ketone-N,N']-copper(II)]-di-μ-chloro]
• CAS: 19319-95-0
• 化学式: C₁₁H₈Cl₂CuN₂O
• 分子量: 318.649
• InChiKey: AALUDWKTMFEFIR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-二吡啶基酮 、 copper dichloride 以 乙腈 为溶剂， 生成 catena-poly[[[bis(2-pyridyl) ketone-N,N']-copper(II)]-di-μ-chloro]
  参考文献：
  名称：

  catena-Poly[[[bis(2-pyridyl) ketone-N,N']copper(II)]-di-μ-chloro]

  摘要：

  The crystal structure of the title compound, [CuCl2(C11H8N2O)](n), has been determined at room temperature, The structure consists of dimeric [Cu2Cl4(DPK)(2)] units [DPK is bis(2-pyridyl) ketone] arranged in linear chains along the b-axis direction. Each Cu atom is surrounded by a distorted octahedral arrangement of two N atoms from a DPK ligand and four Cl atoms, two of which are at appreciably longer distances. Comparisons with the related compound [CuCl2(2,2-bipyridine)](n) are reported.

  DOI：

  10.1107/s0108270199011750