1-acetylferrocene-4-hydroxy-benzoylhydrazone | 188617-36-9

• 英文名称: 1-acetylferrocene-4-hydroxy-benzoylhydrazone
• CAS: 188617-36-9
• 化学式: C₁₉H₁₈FeN₂O₂
• 分子量: 362.211
• InChiKey: QVNQYBOZAMVGLE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  copper(II) choride dihydrate 、 1-acetylferrocene-4-hydroxy-benzoylhydrazone 以 乙醇 为溶剂， 以70%的产率得到[CuCl2(4-acetylferrocene-4-hydroxybenzoylhydrazone)2]*H2O
  参考文献：
  名称：

  SYNTHESIS, ELECTROCHEMICAL BEHAVIOR, SPECTRAL, AND MAGNETIC STUDIES OF COPPER(II) COMPLEXES WITH FERROCENE-CONTAINING HYDRAZONES

  摘要：

  A new series of copper(II) complexes of the stoichiometry [L2CU].nH(2)O and [(HL)(2)CUCl2].2H(2)O, where HL is 1-acetylferrocene-benzoylhydrazone, 1-acetylferrocene-4-chlorobenzoylhydrazone, 1-acetylferrocene-4-hydroxy-benzoylhydrazone or 1-acetylferrocene-4-methylbenzoylhydrazone, HL1, HL2, HL3 or HL4, respectively, were synthesized and characterized. IR data showed that all ligands act as monobasic or neutral bidentates; coordinated to copper ion via the oxygen and azomethine N atoms. ESR spectra and magnetic data showed that [(L-1)(2)CU]-H2O and [(L-3)(2)Cu].2H(2)O are polymeric exhibiting magnetic exchange interaction. ESR data also indicate that all complexes are associated with a d(x2-y2) ground state. The electrochemical behavior of the free ligands and their copper(II) complexes were studied and are discussed.

  DOI：

  10.1081/sim-120016464
• 作为产物：
  描述：

  乙酰基二茂铁 、 4-羟基苯甲酰肼 以 乙醇 为溶剂， 以65%的产率得到1-acetylferrocene-4-hydroxy-benzoylhydrazone
  参考文献：
  名称：

  SYNTHESIS, ELECTROCHEMICAL BEHAVIOR, SPECTRAL, AND MAGNETIC STUDIES OF COPPER(II) COMPLEXES WITH FERROCENE-CONTAINING HYDRAZONES

  摘要：

  A new series of copper(II) complexes of the stoichiometry [L2CU].nH(2)O and [(HL)(2)CUCl2].2H(2)O, where HL is 1-acetylferrocene-benzoylhydrazone, 1-acetylferrocene-4-chlorobenzoylhydrazone, 1-acetylferrocene-4-hydroxy-benzoylhydrazone or 1-acetylferrocene-4-methylbenzoylhydrazone, HL1, HL2, HL3 or HL4, respectively, were synthesized and characterized. IR data showed that all ligands act as monobasic or neutral bidentates; coordinated to copper ion via the oxygen and azomethine N atoms. ESR spectra and magnetic data showed that [(L-1)(2)CU]-H2O and [(L-3)(2)Cu].2H(2)O are polymeric exhibiting magnetic exchange interaction. ESR data also indicate that all complexes are associated with a d(x2-y2) ground state. The electrochemical behavior of the free ligands and their copper(II) complexes were studied and are discussed.

  DOI：

  10.1081/sim-120016464