RuCl(η2-C6H4CHNCH3)(P(CH(CH3)2)3)2 | 299208-31-4

• 英文名称: RuCl(η2-C6H4CHNCH3)(P(CH(CH3)2)3)2
• CAS: 299208-31-4
• 化学式: C₂₆H₅₀ClNP₂Ru
• 分子量: 575.16
• InChiKey: XDBLUVLGERJMGI-MNIFYHRBSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  Ru(H2)Cl(η2-C6H4CHNCH3)(P(CH(CH3)2)3)2 以 氘代苯 为溶剂， 生成 [RuHCl(η2-H2) (P(i-Pr)3)2] 、 RuCl(η2-C6H4CHNCH3)(P(CH(CH3)2)3)2
  参考文献：
  名称：

  Cleavage of H−C(sp²) and C(sp²)−X Bonds (X = Alkyl, Aryl, OR, NR₂):  Facile Decarbonylation, Isonitrile Abstraction, or Dehydrogenation of Aldehydes, Esters, Amides, Amines, and Imines by [RuHCl(PⁱPr₃)₂]₂

  摘要：

  The RuHClL2 fragment (L = (PPr3)-Pr-i) reacts at 25 degrees C with a dozen different G=CHE compounds (G = O, E = R, OR, NR2; G = NR, E = R) to give ct-acid abstraction products, RuHCl(CG)L-2, and E-H. For E-H = C2H5OH, alcohol is decarbonylated in a second step to give an additional CO ligand and CH4. For E-H = HNR(CR'H-2), amine can be dehydrogenated by RuHClL2 to give RuH(H-2)ClL2 and CR'(2)=NR. X-ray crystallographic studies are presented for the DMF decarbonylation intermediate Ru(H)(2)Cl(eta(2)-C(O)NMe2)L-2, where the strong reducing potential of RuHClL2 is manifested in the formally Ru(IV) species obtained from oxidative addition of H-C(O)NMe2. The structure of Ru(H-2)Cl(eta(2)-C6H4CH=NMe)L-2, the product from aryl C-H activation of benzylidenemethylamine, PhHC=NMe, is also presented. This ability to abstract CO, isonitrile, or H-2 is traced to the considerable pi-basicity of RuHCl((PPr3)-Pr-i)(2).

  DOI：

  10.1021/om000390y