1,1,2,2,3,3,4,4,5,5,6-Undecamethyl-6-methylsilanyl-hexasilinane | 182811-46-7

• 英文名称: 1,1,2,2,3,3,4,4,5,5,6-Undecamethyl-6-methylsilanyl-hexasilinane
• CAS: 182811-46-7
• 化学式: C₁₂H₃₈Si₇
• 分子量: 379.032
• InChiKey: IXXURXZVROWTMA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  19.0
• 可旋转键数：
  1.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  1,1,2,2,3,3,4,4,5,5,6-Undecamethyl-6-methylsilanyl-hexasilinane 在 Cp2TiMe 作用下， 以 甲苯 为溶剂， 反应 48.0h， 以18%的产率得到Undecamethylcyclohexasilan
  参考文献：
  名称：

  SiH-containing cyclosilanes and their behaviour in the dehydrogenative polymerization reaction

  摘要：

  To study the behaviour of some cyclosilanes containing Si-H bonds in dehydrogenative polymerization, cyclosilanes with Si-H bonds directly on the ring and cyclosilanes with Si-H bonds in silyl- and disilanyl side chains were synthesized and characterized by the usual spectroscopic and analytical methods. The ease of the polymerization is affected by steric hindrance and oligomers can be formed along with other side products. Only 1,4-bis(silyl)decamethylcyclohexasilane gave a polymer. Cp(2)HfCl(Si(6)Me(11)) was prepared for use as a catalyst.

  DOI：

  10.1016/0022-328x(96)06325-5
• 作为产物：
  描述：

  methyldiphenyl(undecamethylcyclohexasilanyl)silane 在 lithium aluminium tetrahydride 作用下， 以 乙醚 、 甲苯 为溶剂， 反应 1.0h， 生成 1,1,2,2,3,3,4,4,5,5,6-Undecamethyl-6-methylsilanyl-hexasilinane
  参考文献：
  名称：

  SiH-containing cyclosilanes and their behaviour in the dehydrogenative polymerization reaction

  摘要：

  To study the behaviour of some cyclosilanes containing Si-H bonds in dehydrogenative polymerization, cyclosilanes with Si-H bonds directly on the ring and cyclosilanes with Si-H bonds in silyl- and disilanyl side chains were synthesized and characterized by the usual spectroscopic and analytical methods. The ease of the polymerization is affected by steric hindrance and oligomers can be formed along with other side products. Only 1,4-bis(silyl)decamethylcyclohexasilane gave a polymer. Cp(2)HfCl(Si(6)Me(11)) was prepared for use as a catalyst.

  DOI：

  10.1016/0022-328x(96)06325-5