| 1374126-24-5

• CAS: 1374126-24-5
• 化学式: C₅₈H₅₄AgO₂P₂*NO₃
• 分子量: 1014.89
• InChiKey: DYZPYCGTANXBKD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [4-(CH3)2CHC6H4C(O)CHPPh3] 、 silver nitrate 以 甲醇 为溶剂， 以68%的产率得到
  参考文献：
  名称：

  Structural, theoretical and multinuclear NMR study of mercury(II) and silver(I) complexes with two new ambidentate phosphorus ylides

  摘要：

  Reactions of new alpha-ketostabilized phosphorus ylides of the type Ph3P = CHC(O)R (R = 2,4-dichlorophenyl (O) and 4-isopropylphenyl (L-2)) with AgNO(3)and Hg(NO3)(2).H2O, using methanol as a solvent, are reported. The crystal structures of L-2 and [Ag(L-2)(2)(NO3)] (2) have been determined. Characterization of the obtained compounds was also performed by elemental analysis. IR, H-1, P-31 and C-13 NMR. Theoretical studies were carried out on the silver(I) complexes. It was shown that the nitrate ion shows a bonding interaction with the silver ion. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.02.034