(2'-Me3SiCH2-4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine(1-))(C5Me5)lutetium(III)(pentafluoroanilide) | 1010100-70-5

• 英文名称: (2'-Me3SiCH2-4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine(1-))(C5Me5)lutetium(III)(pentafluoroanilide)
• CAS: 1010100-70-5
• 化学式: C₄₇H₆₂F₅LuN₄Si
• 分子量: 981.081
• InChiKey: WZIVRRCYPLQQLK-YEPRCSLYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,3,4,5,6-五氟苯胺 、 (2'-Me3SiCH2-4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine(1-))(C5Me5)lutetium(III)(CH2SiMe3) 以 正己烷 为溶剂， 以60%的产率得到(2'-Me3SiCH2-4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine(1-))(C5Me5)lutetium(III)(pentafluoroanilide)
  参考文献：
  名称：

  Lutetium Alkyls Supported by a Dearomatized and Functionalized Terpyridine Ligand: Preparation of Fluorinated Anilide Complexes

  摘要：

  Lutetium alkyl complexes supported by a monoanionic, tridentate ligand system formed by the dearomatization and junctionalization of a 2,2':6',2 ''-terpyridine have been reacted with 2,4,6-triphenylaniline or the fluorinated anilines 4-F-C6H4NH2 and C6F5NH2 to give both terminal mono(amide) and bis(amide) lutetium(III) complexes, which have been fully characterized. Both [Bu-t(3)(2'-Me3SiCH2)tpy]Lu[NH(2,4,6-Ph-3-C6H2)](2) (3) and [Bu-t(3)(2'-Me3SiCH2)tPy](C5Me5)Lu(NHC6F5) (7) have been structurally characterized. The fluorinated anilide complexes [Bu-t(3)(2'-Me3SiCH2)tpy](C5Me5)Lu(NHArF) (Ar-F = 4-F-C6H4 (6), C6F5 (7)) provide rare examples of lutetium organofluorine complexes, with 7 featuring an intramolecular F center dot center dot center dot H-C interaction that is present in both solid state and solution.

  DOI：

  10.1021/om701076n