| 913746-34-6

• CAS: 913746-34-6
• 化学式: C₁₄H₂₄Cl₂N₂Ni
• 分子量: 349.954
• InChiKey: DILYQZWFOHEETB-LQOYHPPHSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  氯化镍二甲氧基乙烷 、 N,N'-di-cyclohexyl-1,4-diazabuta-1,3-diene 以 二氯甲烷 为溶剂， 以91%的产率得到
  参考文献：
  名称：

  Nickel(II) α-diimine catalysts for the atom transfer radical polymerization of styrene

  摘要：

  The synthesis and evaluation of (Cy)[N,N]NiX2 Complexes (where Cy[N,N] = C6H11-N=CH-CH=N-C6H11; X = Cl, Br) as catalysts for atom transfer radical polymerization are reported. (Cy)[N,N]NiCl2 offers poor control over the polymerization of MMA and styrene due to catalyst insolubility. The more soluble bromo catalyst (Cy)[N,N]NiBr2, promotes rapid styrene polymerization, but with inefficient initiation, affording higher than expected molecular weights based on [M](o)/[I](o) ratios. Utilizing 1-PEBr results in efficient initiation to give low polydispersities (M-w/M-n similar to 1.2) and polystyrene molecular weights that correlate with monomer: initiator ratios. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.06.026