[Fe(meso-tetraphenylporphyrinato)(1-naphthaldehyde)2]SbF6 | 1367737-34-5

• 英文名称: [Fe(meso-tetraphenylporphyrinato)(1-naphthaldehyde)2]SbF6
• CAS: 1367737-34-5
• 化学式: C₆₆H₄₄FeN₄O₂*F₆Sb
• 分子量: 1216.69
• InChiKey: RLSMEMWUDMPQLK-BJPIVMAWSA-H

反应信息

• 作为产物：
  描述：

  [Fe(α,β,γ,δ-mesotetraphenylporphyrinate)]SbF6 、 1-萘甲醛 以 苯 为溶剂， 生成 [Fe(meso-tetraphenylporphyrinato)(1-naphthaldehyde)2]SbF6
  参考文献：
  名称：

  Cationic Iron(III) Porphyrin-Catalyzed [4 + 2] Cycloaddition of Unactivated Aldehydes with Simple Dienes

  摘要：

  Cationic iron(III) porphyrin was found to be an efficient catalyst for the highly chemoselective hetero-Diels Alder-type reaction of aldehydes with 1,3-dienes. The catalyzed process did not require the use of electron-deficient aldehydes such as glyoxylic acid derivatives or activated electron-rich 1,3-dienes such as Danishefslcy's diene and Rawal's diene. The high functional group tolerance and robustness of the catalyst were demonstrated. Further, the potential utility of the catalyst was demonstrated by performing the cycloaddition in the presence of water and by carrying out cycloaddition of an unactivated ketone such as cyclohexanone with a diene.

  DOI：

  10.1021/ja300790x