[PtCl(2,9-dimethyl-1,10-phenanthroline)(ethylene)]2(C(O)C6H2(t-Bu)CMe2C6H2O(t-Bu)C(O)) | 850056-44-9

• 英文名称: [PtCl(2,9-dimethyl-1,10-phenanthroline)(ethylene)]2(C(O)C6H2(t-Bu)CMe2C6H2O(t-Bu)C(O))
• CAS: 850056-44-9
• 化学式: C₅₇H₆₀Cl₂N₄O₃Pt₂
• 分子量: 1310.19
• InChiKey: YCTLBELAQFMHRG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Pt(2,9-dimethyl-1,10-phenanthroline)(ethene)] 、 2,7-di-tert-butyl-9,9-dimethylxanthene-4,5-dicarbonyl dichloride 以 二氯甲烷 为溶剂， 以88%的产率得到[PtCl(2,9-dimethyl-1,10-phenanthroline)(ethylene)]2(C(O)C6H2(t-Bu)CMe2C6H2O(t-Bu)C(O))
  参考文献：
  名称：

  Binuclear platinum complexes of 4,5-disubstituted xanthenes

  摘要：

  New binucleating ligands based on 4,5-disubstituted xanthenes have been prepared. The ligands, which display either mono(acyl, nitrile) or bi-dentate (diimino, dithioamide) functionalities, can be prepared through simple procedures from commercial sources. The molecules have been used to synthesise dinuclear platinum(II) complexes with coordination numbers 4 or 5. Relevant aspects of their spectroscopic characterisation and reactivity are discussed along with the molecular structure of a representative compound. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.11.034