| 400772-57-8

• CAS: 400772-57-8
• 化学式: BF₄*C₃₈H₅₃N₂O₄PRh
• 分子量: 822.534
• InChiKey: UCKBBXAUAZLJHQ-ONEVTFJLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 、 2,2'-(phenylphosphinidene)-bis[N,N-bis(2-methoxyethyl)-benzeneamine] 以 二氯甲烷 为溶剂， 以91%的产率得到
  参考文献：
  名称：

  Synthesis of a tetramethoxy and an amphiphilic tetrahydroxy hemilabile N,P,N-ligand. Coordination behavior towards rhodium(I) and application to hydroformylation of styrene or hydrogenation of trans-cinnamaldehyde

  摘要：

  A tetramethoxy hemilabile N,P,N-ligand and the corresponding amphiphilic tetrahydroxy ligand have been synthesized via ortho-lithiation of N,N-bis(2-methoxyethyl)-benzenamine and N,N-bis[2-(methoxymethoxy)ethyl]-benzenamine, respectively. The coordination behavior of the ligands towards rhodium(I) in solution was investigated and, according to H-1-, C-13- and P-31-NMR data, at room temperature both ligands are coordinated to the metal in a N,P,Rr-tridentate mode without any Rh-O interaction, whereas at low temperature a P-Rh-N bridged dimeric species was also found together with the most favored tridentate monomer. The rhodium complex of the former ligand was applied to hydroformylation of styrene and the complex of the latter ligand was evaluated in the hydrogenation of trans-cinnamaldehyde. (C) 2001 Published by Elsevier Science B.V.

  DOI：

  10.1016/s0022-328x(01)01116-0