(N,N-di-tert-butyloxamidate)Al2Me4 | 1309357-32-1

• 英文名称: (N,N-di-tert-butyloxamidate)Al2Me4
• CAS: 1309357-32-1
• 化学式: C₁₄H₃₀Al₂N₂O₂
• 分子量: 312.367
• InChiKey: MATXYDFMYZJRKC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N,N'-di-tert-butyloxamide 、 三甲基铝 以 二氯甲烷 为溶剂， 以99%的产率得到(N,N-di-tert-butyloxamidate)Al2Me4
  参考文献：
  名称：

  Reactions of group 13 metal trialkyls with oxamides

  摘要：

  Alkyl aluminum-, gallium-, and indium oxamidates Me4Al2(dpoa) (1), Me4Al2(dboa) (2), Me4Ga2(dpoa) (3), Me4Ga2(dboa) (4), (Bu4Ga2)-Bu-t(dpoa) (5) and Me4In2(dboa) (6) (dpoa-H-2 = N,N'-diphenyloxamide, dboa-H-2 = N,N'-di-tert-butyloxamide) have been prepared and characterized. Compounds 1-3, 5 and 6 exist in the form of isomers a only, with a skeleton framework of the molecules consisting of two almost flat, coplanar and fused MNOC2 (M = Al, Ga, In) heterocyclic rings. Depending on the reaction conditions, the compound 4 was obtained as the isomer 4a or as the mixture of two isomers 4a and 4b. Molecular structures of the compounds 1a-6a have been determined by X-ray crystallography. A structure of the isomer 4b was proposed on the basis of NMR spectroscopy. A skeleton framework of the 4b molecule consists of two fused different cycles, GaO2C2 and GaN2C2. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.11.005