Li2(OEt2)2(Me3SiNC(Ph)CH2Ph)2 | 1123198-14-0

• 英文名称: Li2(OEt2)2(Me3SiNC(Ph)CH2Ph)2
• CAS: 1123198-14-0
• 化学式: C₄₂H₆₂Li₂N₄O₂Si₂
• 分子量: 725.033
• InChiKey: PZPMTISMLZGXGQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Li2(OEt2)2(Me3SiNC(Ph)CH2Ph)2 、 氯化铪 以 乙醚 为溶剂， 以82%的产率得到HfCl(Me3SiNC(Ph)CH2Ph)3
  参考文献：
  名称：

  Synthesis and structure of the lithium, zirconium and hafnium N-silyl-N′-benzyl-benzamidinates

  摘要：

  The interaction of LiN(SiMe3)CH2Ph with one equivalent of benzenitrile gave the N-silyl-N'-benzyl-benzamidinato-lithium compound [{Me3SiNC(Ph)N(CH2Ph)}Li(Et2O)](2) (1). The derivative zirconium and hafnium compounds were produced by the treatment of 1 with ZrCl4 or HfCl4 in tetrahydrofuran or diethyl ether at ambient temperature, respectively, with the general formula [Me3SiNC(Ph)N(CH2Ph)](3)MCl (M = Zr (2), Hf (3)). Compounds 1, 2 and 3 were also characterized by X-ray single crystal diffraction and NMR analysis. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.03.112