chlorodimethyltin(IV) [4-ethoxycarbonylpiperazine-1-carbodithioate] | 1228682-54-9

• 英文名称: chlorodimethyltin(IV) [4-ethoxycarbonylpiperazine-1-carbodithioate]
• CAS: 1228682-54-9
• 化学式: C₁₀H₁₉ClN₂O₂S₂Sn
• 分子量: 417.568
• InChiKey: DQWOTBYFULENLR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  sodium 4-(ethoxycarbonyl)piperazine-1-carbodithioate 、 二甲基二氯化锡 以 甲醇 为溶剂， 以69%的产率得到chlorodimethyltin(IV) [4-ethoxycarbonylpiperazine-1-carbodithioate]
  参考文献：
  名称：

  New tetrahedral, square-pyramidal, trigonal-bipyramidal and octahedral organotin(IV) 4-ethoxycarbonylpiperazine-1-carbodithioates: Synthesis, structural properties and biological applications

  摘要：

  This article describes the synthesis of triorganotin(IV)-, chlorodiorganotin(IV)- and diorganotin(IV) 4-ethoxycarbonylpiperazine-1-carbodithioates with general R3SnL {where R = CH3 (1), n-C4H9 (2) and C6H5 (3)}, R2SnClL {where R = CH3 (4), n-C4H9 (5) and C6H5 (6)} and R2SnL2 {where R = CH3 (7), n-C4H9 (8) and C6H5 (9)}, respectively. The coordination behavior of ligand (L) in all compounds was investigated by different analytical techniques such as FT-IR and multinuclear NMR. X-ray single crystal analysis confirmed supramolecular structure for compounds (3) and (4) with distorted trigonal-bipyramidal and distorted square-pyramidal geometries, respectively. The compounds have pronounced antimicrobial (antibacterial and antifungal) potency and moderate insecticidal activity. These compounds also inhibit effectively the activity of urease enzyme. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.03.008