dibutanidobis(2.4.6-trimethylbenzoato)tin | 137198-20-0

• 英文名称: dibutanidobis(2.4.6-trimethylbenzoato)tin
• CAS: 137198-20-0
• 化学式: C₂₈H₄₀O₄Sn
• 分子量: 559.333
• InChiKey: YONYOBCIZSBLLH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,4,6-三甲基苯甲酸 、 二正丁基氧化锡 以 甲苯 为溶剂， 生成 dibutanidobis(2.4.6-trimethylbenzoato)tin
  参考文献：
  名称：

  Structure of dibutanidobis(2,4,6-trimethylbenzoato)tin

  摘要：

  [Sn(C4H9)2(C10H11O2)2], M(r) = 559.3, monoclinic, P2(1)/n, a = 12.07 (2), b = 9.976 (10), c = 22.76 (4) angstrom, beta = 91.60 (10)-degrees, V = 2739.5 angstrom 3, Z = 4, D(x) = 1.356 g cm-3, Mo K-alpha, lambda = 0.71069 angstrom, mu = 9.63 cm-1, F(000) = 1160, T congruent-to 203 K, R = 0.0699 for 2286 unique observed reflections. The title compound is monomeric with distorted octahedral coordination about the Sn atom. The four O atoms of the carboxylate groups and the central Sn atom are coplanar, with a maximum deviation out of the SnO4 plane of 0.007 angstrom. The carboxylate ligands are anisobidentate with short Sn-O bond lengths of 2.116 (9) and 2.088 (9) angstrom and long Sn-O bond lengths of 2.451 (6) and 2.651 (14) angstrom. The butyl groups are approximately trans, with a Bu-Sn-Bu angle of 145.4 (5)-degrees.

  DOI：

  10.1107/s0108270191002950