| 128601-75-2

• CAS: 128601-75-2；220651-27-4
• 化学式: H₃N*I₃In
• 分子量: 512.564
• InChiKey: ACHVTOSMWNZIBN-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 indium 生成 氨 、 indium iodide
  参考文献：
  名称：

  Red'kin, A. N.; Smirnov, V. A.; Sokolova, E. A., Russian Journal of Inorganic Chemistry, 1989, vol. 34, p. 1359 - 1363

  摘要：

  DOI：
• 作为产物：
  描述：

  碘化铵 、 indium 在 o-O₂C₆Br₄ 作用下， 以 氨 为溶剂， 生成
  参考文献：
  名称：

  Electrochemical oxidation of elemental indium in liquid ammonia media

  摘要：

  The electrochemical oxidation of indium metal in solutions of NH4X (X = Cl, Br or I) in liquid ammonia proceeds with an electrochemical efficiency which implies the formation of indium(II) species at the anode. In the case of NH4I-NH3, Raman spectroscopy confirmed the presence of In2I4 in solution; it was not possible to isolate neutral or anionic derivatives of indium(II), since disproportionation occurs on removal of solvent to give indium-(0), -(I) and -(III) derivatives. Mass-balance experiments have been made for these systems. Solutions of NH4I + substituted o-quinone (But2H2C6O2-o or Br4C6O2-o) yielded InI3.3NH3, while with substituted catechols [X4C6(OH)2; X = Cl or Br] the products were [NH4]3[In(O2C6X4)3].Et2O. In the case of a solution of But2H2C6(OH)2-o (H-2dbc) in liquid NH3-Et2O media, the final product is a derivative of the dimeric anion [In2(dbc)4(NH3)2]2-, in a lattice which also contains NH4+, Hdbc- and Et2O. The crystal parameters of [NH4]4[In2(dbc)4(NH3)2].(2Hdbc).2Et2O are monoclinic, space group P2(1)/n, a = 14.464(10), b = 19.194(5), c = 19.560(7) angstrom, beta = 103.72(4)-degrees, Z = 4, R = 0.055. The anion involves two InO5N kernels, with In2O2 cross-linking responsible for the dimerization.

  DOI：

  10.1039/dt9920003061

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: In: MVol., 3.8.2, page 94 - 96
  作者：

  DOI：——

  日期：——
• Klemm, W., Zeitschrift fur anorganische Chemie, 1926, vol. 163, p. 243 - 249
  作者：Klemm, W.

  DOI：——

  日期：——